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Trichodermin (12,13-epoxytrichethec-9-en-4β-yl 4-fluorobenzoate)
In the title trichodermin compound (systematic name: 12,13-epoxytrichothec-9-en-4β-yl 4-fluorobenzoate), C(22)H(25)FO(4), the five-membered ring displays an envelope conformation, whereas the two six-membered rings show the different conformations, viz. chair and half-chair. As for the seven-memb...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007378/ https://www.ncbi.nlm.nih.gov/pubmed/21588390 http://dx.doi.org/10.1107/S1600536810028461 |
| _version_ | 1782194342529597440 |
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| author | Xu, Xu-hui Wang, Zong-cheng Cheng, Jing-li Zhou, Yong Zhao, Jin-hao |
| author_facet | Xu, Xu-hui Wang, Zong-cheng Cheng, Jing-li Zhou, Yong Zhao, Jin-hao |
| author_sort | Xu, Xu-hui |
| collection | PubMed |
| description | In the title trichodermin compound (systematic name: 12,13-epoxytrichothec-9-en-4β-yl 4-fluorobenzoate), C(22)H(25)FO(4), the five-membered ring displays an envelope conformation, whereas the two six-membered rings show the different conformations, viz. chair and half-chair. As for the seven-membered ring, the dihedral angle between the mean planes formed by the four C atoms of the envelope unit and the three C and one O atoms of the six-membered chair is 68.67 (2)°; these two mean planes are nearly perpendicular to the epoxy ring with angles of 87.97 (2)and 88.14 (2)°, respectively. |
| format | Text |
| id | pubmed-3007378 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30073782010-12-30 Trichodermin (12,13-epoxytrichethec-9-en-4β-yl 4-fluorobenzoate) Xu, Xu-hui Wang, Zong-cheng Cheng, Jing-li Zhou, Yong Zhao, Jin-hao Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title trichodermin compound (systematic name: 12,13-epoxytrichothec-9-en-4β-yl 4-fluorobenzoate), C(22)H(25)FO(4), the five-membered ring displays an envelope conformation, whereas the two six-membered rings show the different conformations, viz. chair and half-chair. As for the seven-membered ring, the dihedral angle between the mean planes formed by the four C atoms of the envelope unit and the three C and one O atoms of the six-membered chair is 68.67 (2)°; these two mean planes are nearly perpendicular to the epoxy ring with angles of 87.97 (2)and 88.14 (2)°, respectively. International Union of Crystallography 2010-07-24 /pmc/articles/PMC3007378/ /pubmed/21588390 http://dx.doi.org/10.1107/S1600536810028461 Text en © Xu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Xu, Xu-hui Wang, Zong-cheng Cheng, Jing-li Zhou, Yong Zhao, Jin-hao Trichodermin (12,13-epoxytrichethec-9-en-4β-yl 4-fluorobenzoate) |
| title | Trichodermin (12,13-epoxytrichethec-9-en-4β-yl 4-fluorobenzoate) |
| title_full | Trichodermin (12,13-epoxytrichethec-9-en-4β-yl 4-fluorobenzoate) |
| title_fullStr | Trichodermin (12,13-epoxytrichethec-9-en-4β-yl 4-fluorobenzoate) |
| title_full_unstemmed | Trichodermin (12,13-epoxytrichethec-9-en-4β-yl 4-fluorobenzoate) |
| title_short | Trichodermin (12,13-epoxytrichethec-9-en-4β-yl 4-fluorobenzoate) |
| title_sort | trichodermin (12,13-epoxytrichethec-9-en-4β-yl 4-fluorobenzoate) |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007378/ https://www.ncbi.nlm.nih.gov/pubmed/21588390 http://dx.doi.org/10.1107/S1600536810028461 |
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