4-Methyl-N-[(E)-4-methyl-1-(4-methyl­phenyl­sulfon­yl)-1,2-dihydropyridin-2-yl­idene]benzene­sulfonamide

The reaction of 2-(amino­meth­yl)pyridine and 4-toluene­sulfonyl chloride in CH(2)Cl(2) at pH 8 led to the title compound, C(20)H(20)N(2)O(4)S(2). The aromatic rings are almost perpendicular to each other and the dihedral angles between the aromatic ring planes are 74.33 (9) (central pyridine versus...

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Autores principales: Tabatabaee, Masoumeh, Ghassemzadeh, Mitra, Hesami, Liela, Neumüller, Bernhard
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007380/
https://www.ncbi.nlm.nih.gov/pubmed/21588226
http://dx.doi.org/10.1107/S1600536810025158
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author Tabatabaee, Masoumeh
Ghassemzadeh, Mitra
Hesami, Liela
Neumüller, Bernhard
author_facet Tabatabaee, Masoumeh
Ghassemzadeh, Mitra
Hesami, Liela
Neumüller, Bernhard
author_sort Tabatabaee, Masoumeh
collection PubMed
description The reaction of 2-(amino­meth­yl)pyridine and 4-toluene­sulfonyl chloride in CH(2)Cl(2) at pH 8 led to the title compound, C(20)H(20)N(2)O(4)S(2). The aromatic rings are almost perpendicular to each other and the dihedral angles between the aromatic ring planes are 74.33 (9) (central pyridine versus benzene ring of the tosyl group bonded to the imine functionality), 73.77 (6) (pyridine versus benzene ring of the tosyl group bonded to pyridinic N atom) and 79.83 (9)° (benzene rings of tosyl groups). In the crystal structure, inter­molecular aromatic π–π stacking inter­actions [centroid–centroid separation = 3.6274 (14) Å] help to consolidate the packing.
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spelling pubmed-30073802010-12-30 4-Methyl-N-[(E)-4-methyl-1-(4-methyl­phenyl­sulfon­yl)-1,2-dihydropyridin-2-yl­idene]benzene­sulfonamide Tabatabaee, Masoumeh Ghassemzadeh, Mitra Hesami, Liela Neumüller, Bernhard Acta Crystallogr Sect E Struct Rep Online Organic Papers The reaction of 2-(amino­meth­yl)pyridine and 4-toluene­sulfonyl chloride in CH(2)Cl(2) at pH 8 led to the title compound, C(20)H(20)N(2)O(4)S(2). The aromatic rings are almost perpendicular to each other and the dihedral angles between the aromatic ring planes are 74.33 (9) (central pyridine versus benzene ring of the tosyl group bonded to the imine functionality), 73.77 (6) (pyridine versus benzene ring of the tosyl group bonded to pyridinic N atom) and 79.83 (9)° (benzene rings of tosyl groups). In the crystal structure, inter­molecular aromatic π–π stacking inter­actions [centroid–centroid separation = 3.6274 (14) Å] help to consolidate the packing. International Union of Crystallography 2010-07-03 /pmc/articles/PMC3007380/ /pubmed/21588226 http://dx.doi.org/10.1107/S1600536810025158 Text en © Tabatabaee et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tabatabaee, Masoumeh
Ghassemzadeh, Mitra
Hesami, Liela
Neumüller, Bernhard
4-Methyl-N-[(E)-4-methyl-1-(4-methyl­phenyl­sulfon­yl)-1,2-dihydropyridin-2-yl­idene]benzene­sulfonamide
title 4-Methyl-N-[(E)-4-methyl-1-(4-methyl­phenyl­sulfon­yl)-1,2-dihydropyridin-2-yl­idene]benzene­sulfonamide
title_full 4-Methyl-N-[(E)-4-methyl-1-(4-methyl­phenyl­sulfon­yl)-1,2-dihydropyridin-2-yl­idene]benzene­sulfonamide
title_fullStr 4-Methyl-N-[(E)-4-methyl-1-(4-methyl­phenyl­sulfon­yl)-1,2-dihydropyridin-2-yl­idene]benzene­sulfonamide
title_full_unstemmed 4-Methyl-N-[(E)-4-methyl-1-(4-methyl­phenyl­sulfon­yl)-1,2-dihydropyridin-2-yl­idene]benzene­sulfonamide
title_short 4-Methyl-N-[(E)-4-methyl-1-(4-methyl­phenyl­sulfon­yl)-1,2-dihydropyridin-2-yl­idene]benzene­sulfonamide
title_sort 4-methyl-n-[(e)-4-methyl-1-(4-methyl­phenyl­sulfon­yl)-1,2-dihydropyridin-2-yl­idene]benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007380/
https://www.ncbi.nlm.nih.gov/pubmed/21588226
http://dx.doi.org/10.1107/S1600536810025158
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