N-(4-Chloro­benzo­yl)-2-methyl­benzene­sulfonamide

The asymmetric unit of the title compound, C(14)H(12)ClNO(3)S, contains two independent mol­ecules. The conformations of the N—C bonds in the C—SO(2)—NH—C(O) segments have gauche torsions with respect to the S=O bonds. The mol­ecules are twisted at the S atoms with torsion angles of −54.2 (2) and 63...

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Detalles Bibliográficos
Autores principales: Suchetan, P. A., Gowda, B. Thimme, Foro, Sabine, Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007381/
https://www.ncbi.nlm.nih.gov/pubmed/21588311
http://dx.doi.org/10.1107/S1600536810026759
Descripción
Sumario:The asymmetric unit of the title compound, C(14)H(12)ClNO(3)S, contains two independent mol­ecules. The conformations of the N—C bonds in the C—SO(2)—NH—C(O) segments have gauche torsions with respect to the S=O bonds. The mol­ecules are twisted at the S atoms with torsion angles of −54.2 (2) and 63.8 (2)° in the two mol­ecules. The dihedral angles between the sulfonyl benzene rings and the —SO(2)—NH—C—O segments are 85.0 (1) and 87.0 (1)°. Furthermore, the dihedral angles between the sulfonyl and benzoyl benzene rings are 89.4 (1) and 82.4 (1)° in the two mol­ecules. In the crystal, mol­ecules are linked by N—H⋯O(S) hydrogen bonds.

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