N-(4-Chloro­benzo­yl)-2-methyl­benzene­sulfonamide

The asymmetric unit of the title compound, C(14)H(12)ClNO(3)S, contains two independent mol­ecules. The conformations of the N—C bonds in the C—SO(2)—NH—C(O) segments have gauche torsions with respect to the S=O bonds. The mol­ecules are twisted at the S atoms with torsion angles of −54.2 (2) and 63...

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Detalles Bibliográficos
Autores principales: Suchetan, P. A., Gowda, B. Thimme, Foro, Sabine, Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007381/
https://www.ncbi.nlm.nih.gov/pubmed/21588311
http://dx.doi.org/10.1107/S1600536810026759
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author Suchetan, P. A.
Gowda, B. Thimme
Foro, Sabine
Fuess, Hartmut
author_facet Suchetan, P. A.
Gowda, B. Thimme
Foro, Sabine
Fuess, Hartmut
author_sort Suchetan, P. A.
collection PubMed
description The asymmetric unit of the title compound, C(14)H(12)ClNO(3)S, contains two independent mol­ecules. The conformations of the N—C bonds in the C—SO(2)—NH—C(O) segments have gauche torsions with respect to the S=O bonds. The mol­ecules are twisted at the S atoms with torsion angles of −54.2 (2) and 63.8 (2)° in the two mol­ecules. The dihedral angles between the sulfonyl benzene rings and the —SO(2)—NH—C—O segments are 85.0 (1) and 87.0 (1)°. Furthermore, the dihedral angles between the sulfonyl and benzoyl benzene rings are 89.4 (1) and 82.4 (1)° in the two mol­ecules. In the crystal, mol­ecules are linked by N—H⋯O(S) hydrogen bonds.
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spelling pubmed-30073812010-12-30 N-(4-Chloro­benzo­yl)-2-methyl­benzene­sulfonamide Suchetan, P. A. Gowda, B. Thimme Foro, Sabine Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(14)H(12)ClNO(3)S, contains two independent mol­ecules. The conformations of the N—C bonds in the C—SO(2)—NH—C(O) segments have gauche torsions with respect to the S=O bonds. The mol­ecules are twisted at the S atoms with torsion angles of −54.2 (2) and 63.8 (2)° in the two mol­ecules. The dihedral angles between the sulfonyl benzene rings and the —SO(2)—NH—C—O segments are 85.0 (1) and 87.0 (1)°. Furthermore, the dihedral angles between the sulfonyl and benzoyl benzene rings are 89.4 (1) and 82.4 (1)° in the two mol­ecules. In the crystal, mol­ecules are linked by N—H⋯O(S) hydrogen bonds. International Union of Crystallography 2010-07-14 /pmc/articles/PMC3007381/ /pubmed/21588311 http://dx.doi.org/10.1107/S1600536810026759 Text en © Suchetan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Suchetan, P. A.
Gowda, B. Thimme
Foro, Sabine
Fuess, Hartmut
N-(4-Chloro­benzo­yl)-2-methyl­benzene­sulfonamide
title N-(4-Chloro­benzo­yl)-2-methyl­benzene­sulfonamide
title_full N-(4-Chloro­benzo­yl)-2-methyl­benzene­sulfonamide
title_fullStr N-(4-Chloro­benzo­yl)-2-methyl­benzene­sulfonamide
title_full_unstemmed N-(4-Chloro­benzo­yl)-2-methyl­benzene­sulfonamide
title_short N-(4-Chloro­benzo­yl)-2-methyl­benzene­sulfonamide
title_sort n-(4-chloro­benzo­yl)-2-methyl­benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007381/
https://www.ncbi.nlm.nih.gov/pubmed/21588311
http://dx.doi.org/10.1107/S1600536810026759
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AT gowdabthimme n4chlorobenzoyl2methylbenzenesulfonamide
AT forosabine n4chlorobenzoyl2methylbenzenesulfonamide
AT fuesshartmut n4chlorobenzoyl2methylbenzenesulfonamide

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