A binuclear molybdenum oxyfluoride: μ-oxido-bis­[(2,2′-bipyrid­yl)fluoridodioxidomolybdenum(VI)]

The title compound, [Mo(2)F(2)O(5)(C(10)H(8)N(2))(2)], is a centrosymmetric binuclear molybdenum(VI) species with the metal atoms in a distorted octa­hedral environment. The coordination geometries of the symmetry-equivalent molybdenum sites are defined by the cis-terminal oxide groups and the N-ato...

Descripción completa

Detalles Bibliográficos
Autores principales: DeBurgomaster, Paul, Zubieta, Jon
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007386/
https://www.ncbi.nlm.nih.gov/pubmed/21588148
http://dx.doi.org/10.1107/S1600536810026383
_version_ 1782194344400257024
author DeBurgomaster, Paul
Zubieta, Jon
author_facet DeBurgomaster, Paul
Zubieta, Jon
author_sort DeBurgomaster, Paul
collection PubMed
description The title compound, [Mo(2)F(2)O(5)(C(10)H(8)N(2))(2)], is a centrosymmetric binuclear molybdenum(VI) species with the metal atoms in a distorted octa­hedral environment. The coordination geometries of the symmetry-equivalent molybdenum sites are defined by the cis-terminal oxide groups and the N-atom donors of the bipyridyl ligand in the equatorial plane with axial F and bridging O atoms. The bridging O atom occupies a center of symmetry. The mol­ecules stack in the a-axis direction, and the crystal packing is stabilized by weak intra- and inter­molecular C—H⋯O and C—H⋯F hydrogen bonds.
format Text
id pubmed-3007386
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30073862010-12-30 A binuclear molybdenum oxyfluoride: μ-oxido-bis­[(2,2′-bipyrid­yl)fluoridodioxidomolybdenum(VI)] DeBurgomaster, Paul Zubieta, Jon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mo(2)F(2)O(5)(C(10)H(8)N(2))(2)], is a centrosymmetric binuclear molybdenum(VI) species with the metal atoms in a distorted octa­hedral environment. The coordination geometries of the symmetry-equivalent molybdenum sites are defined by the cis-terminal oxide groups and the N-atom donors of the bipyridyl ligand in the equatorial plane with axial F and bridging O atoms. The bridging O atom occupies a center of symmetry. The mol­ecules stack in the a-axis direction, and the crystal packing is stabilized by weak intra- and inter­molecular C—H⋯O and C—H⋯F hydrogen bonds. International Union of Crystallography 2010-07-10 /pmc/articles/PMC3007386/ /pubmed/21588148 http://dx.doi.org/10.1107/S1600536810026383 Text en © DeBurgomaster and Zubieta 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
DeBurgomaster, Paul
Zubieta, Jon
A binuclear molybdenum oxyfluoride: μ-oxido-bis­[(2,2′-bipyrid­yl)fluoridodioxidomolybdenum(VI)]
title A binuclear molybdenum oxyfluoride: μ-oxido-bis­[(2,2′-bipyrid­yl)fluoridodioxidomolybdenum(VI)]
title_full A binuclear molybdenum oxyfluoride: μ-oxido-bis­[(2,2′-bipyrid­yl)fluoridodioxidomolybdenum(VI)]
title_fullStr A binuclear molybdenum oxyfluoride: μ-oxido-bis­[(2,2′-bipyrid­yl)fluoridodioxidomolybdenum(VI)]
title_full_unstemmed A binuclear molybdenum oxyfluoride: μ-oxido-bis­[(2,2′-bipyrid­yl)fluoridodioxidomolybdenum(VI)]
title_short A binuclear molybdenum oxyfluoride: μ-oxido-bis­[(2,2′-bipyrid­yl)fluoridodioxidomolybdenum(VI)]
title_sort binuclear molybdenum oxyfluoride: μ-oxido-bis­[(2,2′-bipyrid­yl)fluoridodioxidomolybdenum(vi)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007386/
https://www.ncbi.nlm.nih.gov/pubmed/21588148
http://dx.doi.org/10.1107/S1600536810026383
work_keys_str_mv AT deburgomasterpaul abinuclearmolybdenumoxyfluoridemoxidobis22bipyridylfluoridodioxidomolybdenumvi
AT zubietajon abinuclearmolybdenumoxyfluoridemoxidobis22bipyridylfluoridodioxidomolybdenumvi
AT deburgomasterpaul binuclearmolybdenumoxyfluoridemoxidobis22bipyridylfluoridodioxidomolybdenumvi
AT zubietajon binuclearmolybdenumoxyfluoridemoxidobis22bipyridylfluoridodioxidomolybdenumvi

Ejemplares similares