Tris(2-amino-1,3-thia­zole-κN (3))(7-oxa­bicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato-κ(3) O (2),O (3),O (7))cadmium(II) dihydrate

In the crystal structure of the title complex, [Cd(C(8)H(8)O(5))(C(3)H(4)N(2)S)(3)]·2H(2)O, the Cd(II) atom exhibits a slightly distorted octa­hedral CdO(3)N(3) coordination, defined by the bridging O atom of the bicyclo­heptane unit, two O atoms from the carboxyl­ate groups and by three N atoms fro...

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Detalles Bibliográficos
Autores principales: Wang, Na, Wu, Yi-Zhou, Lin, Qiu-Yue
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007392/
https://www.ncbi.nlm.nih.gov/pubmed/21588187
http://dx.doi.org/10.1107/S1600536810027170
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author Wang, Na
Wu, Yi-Zhou
Lin, Qiu-Yue
author_facet Wang, Na
Wu, Yi-Zhou
Lin, Qiu-Yue
author_sort Wang, Na
collection PubMed
description In the crystal structure of the title complex, [Cd(C(8)H(8)O(5))(C(3)H(4)N(2)S)(3)]·2H(2)O, the Cd(II) atom exhibits a slightly distorted octa­hedral CdO(3)N(3) coordination, defined by the bridging O atom of the bicyclo­heptane unit, two O atoms from the carboxyl­ate groups and by three N atoms from three 2-amino­thia­zole ligands. Uncoordinated lattice water mol­ecules are also present in the crystal structure. N—H⋯O and O—H⋯O hydrogen-bonding inter­actions link the components into a three-dimensional structure.
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spelling pubmed-30073922010-12-30 Tris(2-amino-1,3-thia­zole-κN (3))(7-oxa­bicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato-κ(3) O (2),O (3),O (7))cadmium(II) dihydrate Wang, Na Wu, Yi-Zhou Lin, Qiu-Yue Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title complex, [Cd(C(8)H(8)O(5))(C(3)H(4)N(2)S)(3)]·2H(2)O, the Cd(II) atom exhibits a slightly distorted octa­hedral CdO(3)N(3) coordination, defined by the bridging O atom of the bicyclo­heptane unit, two O atoms from the carboxyl­ate groups and by three N atoms from three 2-amino­thia­zole ligands. Uncoordinated lattice water mol­ecules are also present in the crystal structure. N—H⋯O and O—H⋯O hydrogen-bonding inter­actions link the components into a three-dimensional structure. International Union of Crystallography 2010-07-17 /pmc/articles/PMC3007392/ /pubmed/21588187 http://dx.doi.org/10.1107/S1600536810027170 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Na
Wu, Yi-Zhou
Lin, Qiu-Yue
Tris(2-amino-1,3-thia­zole-κN (3))(7-oxa­bicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato-κ(3) O (2),O (3),O (7))cadmium(II) dihydrate
title Tris(2-amino-1,3-thia­zole-κN (3))(7-oxa­bicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato-κ(3) O (2),O (3),O (7))cadmium(II) dihydrate
title_full Tris(2-amino-1,3-thia­zole-κN (3))(7-oxa­bicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato-κ(3) O (2),O (3),O (7))cadmium(II) dihydrate
title_fullStr Tris(2-amino-1,3-thia­zole-κN (3))(7-oxa­bicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato-κ(3) O (2),O (3),O (7))cadmium(II) dihydrate
title_full_unstemmed Tris(2-amino-1,3-thia­zole-κN (3))(7-oxa­bicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato-κ(3) O (2),O (3),O (7))cadmium(II) dihydrate
title_short Tris(2-amino-1,3-thia­zole-κN (3))(7-oxa­bicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato-κ(3) O (2),O (3),O (7))cadmium(II) dihydrate
title_sort tris(2-amino-1,3-thia­zole-κn (3))(7-oxa­bicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato-κ(3) o (2),o (3),o (7))cadmium(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007392/
https://www.ncbi.nlm.nih.gov/pubmed/21588187
http://dx.doi.org/10.1107/S1600536810027170
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AT wuyizhou tris2amino13thiazolekn37oxabicyclo221heptane23dicarboxylatok3o2o3o7cadmiumiidihydrate
AT linqiuyue tris2amino13thiazolekn37oxabicyclo221heptane23dicarboxylatok3o2o3o7cadmiumiidihydrate

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