Bis(μ-5-carboxyl­atotetra­zolido)bis­[aqua­(2,2′-bipyrid­yl)cadmium(II)]

In the title dinuclear Cd(II) complex, [Cd(2)(C(2)N(4)O(2))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], each Cd atom is in a slightly distorted octa­hedral coordination by two N atoms and one O atom of two 1H-tetra­zole-5-carboxyl­ate (TZC) ligands, two N atoms of a 2,2′-bipyridyl ligand and one water O atom....

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Detalles Bibliográficos
Autores principales: Sun, Shuang-Jiao, Deng, Ji-Hua, Liu, Ti-Lou
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007395/
https://www.ncbi.nlm.nih.gov/pubmed/21588205
http://dx.doi.org/10.1107/S1600536810027613
Descripción
Sumario:In the title dinuclear Cd(II) complex, [Cd(2)(C(2)N(4)O(2))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], each Cd atom is in a slightly distorted octa­hedral coordination by two N atoms and one O atom of two 1H-tetra­zole-5-carboxyl­ate (TZC) ligands, two N atoms of a 2,2′-bipyridyl ligand and one water O atom. The TZC ligand acts in a tridentate N,O-chelating N-bridging mode to two symmetry-equivalent Cd(II) atoms. The complex reveals mol­ecular C (i) symmetry. Extensive O—H⋯O hydrogen bonding plays an important role in the crystal packing.

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