Bis(μ-5-carboxyl­atotetra­zolido)bis­[aqua­(2,2′-bipyrid­yl)cadmium(II)]

In the title dinuclear Cd(II) complex, [Cd(2)(C(2)N(4)O(2))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], each Cd atom is in a slightly distorted octa­hedral coordination by two N atoms and one O atom of two 1H-tetra­zole-5-carboxyl­ate (TZC) ligands, two N atoms of a 2,2′-bipyridyl ligand and one water O atom....

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Detalles Bibliográficos
Autores principales: Sun, Shuang-Jiao, Deng, Ji-Hua, Liu, Ti-Lou
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007395/
https://www.ncbi.nlm.nih.gov/pubmed/21588205
http://dx.doi.org/10.1107/S1600536810027613
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author Sun, Shuang-Jiao
Deng, Ji-Hua
Liu, Ti-Lou
author_facet Sun, Shuang-Jiao
Deng, Ji-Hua
Liu, Ti-Lou
author_sort Sun, Shuang-Jiao
collection PubMed
description In the title dinuclear Cd(II) complex, [Cd(2)(C(2)N(4)O(2))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], each Cd atom is in a slightly distorted octa­hedral coordination by two N atoms and one O atom of two 1H-tetra­zole-5-carboxyl­ate (TZC) ligands, two N atoms of a 2,2′-bipyridyl ligand and one water O atom. The TZC ligand acts in a tridentate N,O-chelating N-bridging mode to two symmetry-equivalent Cd(II) atoms. The complex reveals mol­ecular C (i) symmetry. Extensive O—H⋯O hydrogen bonding plays an important role in the crystal packing.
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spelling pubmed-30073952010-12-30 Bis(μ-5-carboxyl­atotetra­zolido)bis­[aqua­(2,2′-bipyrid­yl)cadmium(II)] Sun, Shuang-Jiao Deng, Ji-Hua Liu, Ti-Lou Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear Cd(II) complex, [Cd(2)(C(2)N(4)O(2))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], each Cd atom is in a slightly distorted octa­hedral coordination by two N atoms and one O atom of two 1H-tetra­zole-5-carboxyl­ate (TZC) ligands, two N atoms of a 2,2′-bipyridyl ligand and one water O atom. The TZC ligand acts in a tridentate N,O-chelating N-bridging mode to two symmetry-equivalent Cd(II) atoms. The complex reveals mol­ecular C (i) symmetry. Extensive O—H⋯O hydrogen bonding plays an important role in the crystal packing. International Union of Crystallography 2010-07-21 /pmc/articles/PMC3007395/ /pubmed/21588205 http://dx.doi.org/10.1107/S1600536810027613 Text en © Sun et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sun, Shuang-Jiao
Deng, Ji-Hua
Liu, Ti-Lou
Bis(μ-5-carboxyl­atotetra­zolido)bis­[aqua­(2,2′-bipyrid­yl)cadmium(II)]
title Bis(μ-5-carboxyl­atotetra­zolido)bis­[aqua­(2,2′-bipyrid­yl)cadmium(II)]
title_full Bis(μ-5-carboxyl­atotetra­zolido)bis­[aqua­(2,2′-bipyrid­yl)cadmium(II)]
title_fullStr Bis(μ-5-carboxyl­atotetra­zolido)bis­[aqua­(2,2′-bipyrid­yl)cadmium(II)]
title_full_unstemmed Bis(μ-5-carboxyl­atotetra­zolido)bis­[aqua­(2,2′-bipyrid­yl)cadmium(II)]
title_short Bis(μ-5-carboxyl­atotetra­zolido)bis­[aqua­(2,2′-bipyrid­yl)cadmium(II)]
title_sort bis(μ-5-carboxyl­atotetra­zolido)bis­[aqua­(2,2′-bipyrid­yl)cadmium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007395/
https://www.ncbi.nlm.nih.gov/pubmed/21588205
http://dx.doi.org/10.1107/S1600536810027613
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