Tetra­aqua­(1,10-phenanthroline-κ(2) N,N′)cadmium(II) sulfate dihydrate

In the title mononuclear complex, [Cd(C(12)H(8)N(2))(H(2)O)(4)]SO(4)·2H(2)O, the coordination geometry around the Cd(II) atom is a distorted octa­hedron, with two aqua ligands occupying the axial positions. Inter­molecular O—H⋯O hydrogen bonds lead to the formation of a two-dimensional layer structu...

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Detalles Bibliográficos
Autores principales: Zhang, Yuan-Yuan, Jin, Qiong-Hua, Yang, Wei, Zhang, Cun-Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007401/
https://www.ncbi.nlm.nih.gov/pubmed/21588195
http://dx.doi.org/10.1107/S1600536810028175
Descripción
Sumario:In the title mononuclear complex, [Cd(C(12)H(8)N(2))(H(2)O)(4)]SO(4)·2H(2)O, the coordination geometry around the Cd(II) atom is a distorted octa­hedron, with two aqua ligands occupying the axial positions. Inter­molecular O—H⋯O hydrogen bonds lead to the formation of a two-dimensional layer structure parallel to (001). The layers are connected by π–π inter­actions between the pyridyl and benzene rings of the phenanthroline ligands [centroid–centroid distances = 3.591 (1) and 3.610 (1) Å].

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