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Tetraaqua(1,10-phenanthroline-κ(2) N,N′)cadmium(II) sulfate dihydrate
In the title mononuclear complex, [Cd(C(12)H(8)N(2))(H(2)O)(4)]SO(4)·2H(2)O, the coordination geometry around the Cd(II) atom is a distorted octahedron, with two aqua ligands occupying the axial positions. Intermolecular O—H⋯O hydrogen bonds lead to the formation of a two-dimensional layer structu...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007401/ https://www.ncbi.nlm.nih.gov/pubmed/21588195 http://dx.doi.org/10.1107/S1600536810028175 |
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| author | Zhang, Yuan-Yuan Jin, Qiong-Hua Yang, Wei Zhang, Cun-Lin |
| author_facet | Zhang, Yuan-Yuan Jin, Qiong-Hua Yang, Wei Zhang, Cun-Lin |
| author_sort | Zhang, Yuan-Yuan |
| collection | PubMed |
| description | In the title mononuclear complex, [Cd(C(12)H(8)N(2))(H(2)O)(4)]SO(4)·2H(2)O, the coordination geometry around the Cd(II) atom is a distorted octahedron, with two aqua ligands occupying the axial positions. Intermolecular O—H⋯O hydrogen bonds lead to the formation of a two-dimensional layer structure parallel to (001). The layers are connected by π–π interactions between the pyridyl and benzene rings of the phenanthroline ligands [centroid–centroid distances = 3.591 (1) and 3.610 (1) Å]. |
| format | Text |
| id | pubmed-3007401 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30074012010-12-30 Tetraaqua(1,10-phenanthroline-κ(2) N,N′)cadmium(II) sulfate dihydrate Zhang, Yuan-Yuan Jin, Qiong-Hua Yang, Wei Zhang, Cun-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear complex, [Cd(C(12)H(8)N(2))(H(2)O)(4)]SO(4)·2H(2)O, the coordination geometry around the Cd(II) atom is a distorted octahedron, with two aqua ligands occupying the axial positions. Intermolecular O—H⋯O hydrogen bonds lead to the formation of a two-dimensional layer structure parallel to (001). The layers are connected by π–π interactions between the pyridyl and benzene rings of the phenanthroline ligands [centroid–centroid distances = 3.591 (1) and 3.610 (1) Å]. International Union of Crystallography 2010-07-21 /pmc/articles/PMC3007401/ /pubmed/21588195 http://dx.doi.org/10.1107/S1600536810028175 Text en © Zhang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhang, Yuan-Yuan Jin, Qiong-Hua Yang, Wei Zhang, Cun-Lin Tetraaqua(1,10-phenanthroline-κ(2) N,N′)cadmium(II) sulfate dihydrate |
| title | Tetraaqua(1,10-phenanthroline-κ(2)
N,N′)cadmium(II) sulfate dihydrate |
| title_full | Tetraaqua(1,10-phenanthroline-κ(2)
N,N′)cadmium(II) sulfate dihydrate |
| title_fullStr | Tetraaqua(1,10-phenanthroline-κ(2)
N,N′)cadmium(II) sulfate dihydrate |
| title_full_unstemmed | Tetraaqua(1,10-phenanthroline-κ(2)
N,N′)cadmium(II) sulfate dihydrate |
| title_short | Tetraaqua(1,10-phenanthroline-κ(2)
N,N′)cadmium(II) sulfate dihydrate |
| title_sort | tetraaqua(1,10-phenanthroline-κ(2)
n,n′)cadmium(ii) sulfate dihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007401/ https://www.ncbi.nlm.nih.gov/pubmed/21588195 http://dx.doi.org/10.1107/S1600536810028175 |
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