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Di-μ-nicotinato-κ(2) N:O;κ(2) O:N-bis[aquabis(4-bromobenzyl)(nicotinato-κ(2) O,O′)tin(IV)]
Two nicotinate binding modes are observed in the dinuclear title compound, [Sn(2)(C(7)H(6)Br)(4)(C(6)H(4)NO(2))(4)(H(2)O)(2)]: in the first, a terminal O,O′-chelating molecule binds to a water-coordinated diorganotin cation, while the second mode corresponds to an O:N-bridging molecule which binds t...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007403/ https://www.ncbi.nlm.nih.gov/pubmed/21588088 http://dx.doi.org/10.1107/S1600536810028643 |
| _version_ | 1782194348469780480 |
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| author | Keng, Chun Thy Lo, Kong Mun Ng, Seik Weng |
| author_facet | Keng, Chun Thy Lo, Kong Mun Ng, Seik Weng |
| author_sort | Keng, Chun Thy |
| collection | PubMed |
| description | Two nicotinate binding modes are observed in the dinuclear title compound, [Sn(2)(C(7)H(6)Br)(4)(C(6)H(4)NO(2))(4)(H(2)O)(2)]: in the first, a terminal O,O′-chelating molecule binds to a water-coordinated diorganotin cation, while the second mode corresponds to an O:N-bridging molecule which binds to two cations. The two Sn atoms exist in trans-C(2)SnNO(4) pentagonal-bipyramidal geometries. Adjacent dinuclear units are linked by O—H⋯N hydrogen bonds, generating a linear chain, which propagates in the b-axis direction. O—H⋯O interactions are also observed. |
| format | Text |
| id | pubmed-3007403 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30074032010-12-30 Di-μ-nicotinato-κ(2) N:O;κ(2) O:N-bis[aquabis(4-bromobenzyl)(nicotinato-κ(2) O,O′)tin(IV)] Keng, Chun Thy Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Two nicotinate binding modes are observed in the dinuclear title compound, [Sn(2)(C(7)H(6)Br)(4)(C(6)H(4)NO(2))(4)(H(2)O)(2)]: in the first, a terminal O,O′-chelating molecule binds to a water-coordinated diorganotin cation, while the second mode corresponds to an O:N-bridging molecule which binds to two cations. The two Sn atoms exist in trans-C(2)SnNO(4) pentagonal-bipyramidal geometries. Adjacent dinuclear units are linked by O—H⋯N hydrogen bonds, generating a linear chain, which propagates in the b-axis direction. O—H⋯O interactions are also observed. International Union of Crystallography 2010-07-24 /pmc/articles/PMC3007403/ /pubmed/21588088 http://dx.doi.org/10.1107/S1600536810028643 Text en © Keng et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Keng, Chun Thy Lo, Kong Mun Ng, Seik Weng Di-μ-nicotinato-κ(2) N:O;κ(2) O:N-bis[aquabis(4-bromobenzyl)(nicotinato-κ(2) O,O′)tin(IV)] |
| title | Di-μ-nicotinato-κ(2)
N:O;κ(2)
O:N-bis[aquabis(4-bromobenzyl)(nicotinato-κ(2)
O,O′)tin(IV)] |
| title_full | Di-μ-nicotinato-κ(2)
N:O;κ(2)
O:N-bis[aquabis(4-bromobenzyl)(nicotinato-κ(2)
O,O′)tin(IV)] |
| title_fullStr | Di-μ-nicotinato-κ(2)
N:O;κ(2)
O:N-bis[aquabis(4-bromobenzyl)(nicotinato-κ(2)
O,O′)tin(IV)] |
| title_full_unstemmed | Di-μ-nicotinato-κ(2)
N:O;κ(2)
O:N-bis[aquabis(4-bromobenzyl)(nicotinato-κ(2)
O,O′)tin(IV)] |
| title_short | Di-μ-nicotinato-κ(2)
N:O;κ(2)
O:N-bis[aquabis(4-bromobenzyl)(nicotinato-κ(2)
O,O′)tin(IV)] |
| title_sort | di-μ-nicotinato-κ(2)
n:o;κ(2)
o:n-bis[aquabis(4-bromobenzyl)(nicotinato-κ(2)
o,o′)tin(iv)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007403/ https://www.ncbi.nlm.nih.gov/pubmed/21588088 http://dx.doi.org/10.1107/S1600536810028643 |
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