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5,8-Dibromo-2,11-dithia­[3,3](2,6)pyridino­paracyclo­phane

The title compound, C(15)H(13)Br(2)NS(2) [systematic name: 1(2),1(5)-dibromo-2,7-dithia-1(1,4)-benzena-5(2,6)-pyridinaocta­phane], contains a dibromo-substituted benzene ring and a pyridine ring that are linked by a pair of bridging —CH(2)SCH(2)— groups. There is a weak π–π inter­action between the...

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Detalles Bibliográficos
Autores principales: Li, Si-Si, Zhang, Bei, Zhang, Hong-Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007406/
https://www.ncbi.nlm.nih.gov/pubmed/21588414
http://dx.doi.org/10.1107/S1600536810028850
Descripción
Sumario:The title compound, C(15)H(13)Br(2)NS(2) [systematic name: 1(2),1(5)-dibromo-2,7-dithia-1(1,4)-benzena-5(2,6)-pyridinaocta­phane], contains a dibromo-substituted benzene ring and a pyridine ring that are linked by a pair of bridging —CH(2)SCH(2)— groups. There is a weak π–π inter­action between the rings, the distance between the ring centroids being 3.572 (4) Å. The rings are not parallel, but form a dihedral angle of 18.29 (4)°.