(OC-6-33)-(2,2′-Bipyridine-κ(2) N,N′)trimeth­yl(2-methyl­sulfanyl-2-thia­zoline-κN)platinum(IV) tetra­fluoridoborate

The asymmetric unit of the title complex, [Pt(CH(3))(3)(C(10)H(8)N(2))(C(4)H(7)NS(2))]BF(4), contains two crystallographically independent mol­ecules. The Pt(IV) atom in each complex cation exhibits a distorted octa­hedral coordination geometry, built up by three methyl ligands in a facial binding f...

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Detalles Bibliográficos
Autores principales: Vetter, Cornelia, Bruhn, Clemens, Steinborn, Dirk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007407/
https://www.ncbi.nlm.nih.gov/pubmed/21588173
http://dx.doi.org/10.1107/S1600536810027546
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author Vetter, Cornelia
Bruhn, Clemens
Steinborn, Dirk
author_facet Vetter, Cornelia
Bruhn, Clemens
Steinborn, Dirk
author_sort Vetter, Cornelia
collection PubMed
description The asymmetric unit of the title complex, [Pt(CH(3))(3)(C(10)H(8)N(2))(C(4)H(7)NS(2))]BF(4), contains two crystallographically independent mol­ecules. The Pt(IV) atom in each complex cation exhibits a distorted octa­hedral coordination geometry, built up by three methyl ligands in a facial binding fashion, a bipyridine ligand and a monodentately N-bound 2-methyl­sulfanyl-2-thia­zoline ligand (configuration index: OC-6–33). In the crystal structure, weak inter­molecular C—H⋯F hydrogen bonds are found between the complex cations and BF(4) (−) anions.
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spelling pubmed-30074072010-12-30 (OC-6-33)-(2,2′-Bipyridine-κ(2) N,N′)trimeth­yl(2-methyl­sulfanyl-2-thia­zoline-κN)platinum(IV) tetra­fluoridoborate Vetter, Cornelia Bruhn, Clemens Steinborn, Dirk Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Pt(CH(3))(3)(C(10)H(8)N(2))(C(4)H(7)NS(2))]BF(4), contains two crystallographically independent mol­ecules. The Pt(IV) atom in each complex cation exhibits a distorted octa­hedral coordination geometry, built up by three methyl ligands in a facial binding fashion, a bipyridine ligand and a monodentately N-bound 2-methyl­sulfanyl-2-thia­zoline ligand (configuration index: OC-6–33). In the crystal structure, weak inter­molecular C—H⋯F hydrogen bonds are found between the complex cations and BF(4) (−) anions. International Union of Crystallography 2010-07-17 /pmc/articles/PMC3007407/ /pubmed/21588173 http://dx.doi.org/10.1107/S1600536810027546 Text en © Vetter et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Vetter, Cornelia
Bruhn, Clemens
Steinborn, Dirk
(OC-6-33)-(2,2′-Bipyridine-κ(2) N,N′)trimeth­yl(2-methyl­sulfanyl-2-thia­zoline-κN)platinum(IV) tetra­fluoridoborate
title (OC-6-33)-(2,2′-Bipyridine-κ(2) N,N′)trimeth­yl(2-methyl­sulfanyl-2-thia­zoline-κN)platinum(IV) tetra­fluoridoborate
title_full (OC-6-33)-(2,2′-Bipyridine-κ(2) N,N′)trimeth­yl(2-methyl­sulfanyl-2-thia­zoline-κN)platinum(IV) tetra­fluoridoborate
title_fullStr (OC-6-33)-(2,2′-Bipyridine-κ(2) N,N′)trimeth­yl(2-methyl­sulfanyl-2-thia­zoline-κN)platinum(IV) tetra­fluoridoborate
title_full_unstemmed (OC-6-33)-(2,2′-Bipyridine-κ(2) N,N′)trimeth­yl(2-methyl­sulfanyl-2-thia­zoline-κN)platinum(IV) tetra­fluoridoborate
title_short (OC-6-33)-(2,2′-Bipyridine-κ(2) N,N′)trimeth­yl(2-methyl­sulfanyl-2-thia­zoline-κN)platinum(IV) tetra­fluoridoborate
title_sort (oc-6-33)-(2,2′-bipyridine-κ(2) n,n′)trimeth­yl(2-methyl­sulfanyl-2-thia­zoline-κn)platinum(iv) tetra­fluoridoborate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007407/
https://www.ncbi.nlm.nih.gov/pubmed/21588173
http://dx.doi.org/10.1107/S1600536810027546
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AT bruhnclemens oc63322bipyridinek2nntrimethyl2methylsulfanyl2thiazolineknplatinumivtetrafluoridoborate
AT steinborndirk oc63322bipyridinek2nntrimethyl2methylsulfanyl2thiazolineknplatinumivtetrafluoridoborate

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