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Racemic tricarbon­yl(η(6)-7-meth­oxy­flavan)chromium(0)

In the title compound [systematic name: tricarbonyl(η(6)-7-methoxy-2-phenyl-3,4-dihydro-2H-1-benzopyran)chromium(0)], [Cr(C(16)H(16)O(2))(CO)(3)], the Cr(CO)(3) unit is coordinated by the phenyl­ene ring of the flavan ligand, exhibiting a three-legged piano-stool conformation, with a point to plane...

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Autores principales: van Tonder, Johannes. H., Bezuidenhoudt, Barend C. B., Janse van Rensburg, J. Marthinus
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007425/
https://www.ncbi.nlm.nih.gov/pubmed/21588147
http://dx.doi.org/10.1107/S1600536810024992
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author van Tonder, Johannes. H.
Bezuidenhoudt, Barend C. B.
Janse van Rensburg, J. Marthinus
author_facet van Tonder, Johannes. H.
Bezuidenhoudt, Barend C. B.
Janse van Rensburg, J. Marthinus
author_sort van Tonder, Johannes. H.
collection PubMed
description In the title compound [systematic name: tricarbonyl(η(6)-7-methoxy-2-phenyl-3,4-dihydro-2H-1-benzopyran)chromium(0)], [Cr(C(16)H(16)O(2))(CO)(3)], the Cr(CO)(3) unit is coordinated by the phenyl­ene ring of the flavan ligand, exhibiting a three-legged piano-stool conformation, with a point to plane distance of 1.750 (1) Å. The phenyl ring is twisted away from the fused ring system by 36.49 (5)° (r.m.s. deviation = 0.027 Å; fitted atoms are the C(6) ring and the attached fused-ring C and O atoms). The dihydro­pyran ring displays a distorted envelope configuration by displacement of the phenyl-bearing and the adjacent ring C atoms from the fused-ring system plane by 0.356 (2) and 0.402 (2) Å, respectively.
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spelling pubmed-30074252010-12-30 Racemic tricarbon­yl(η(6)-7-meth­oxy­flavan)chromium(0) van Tonder, Johannes. H. Bezuidenhoudt, Barend C. B. Janse van Rensburg, J. Marthinus Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound [systematic name: tricarbonyl(η(6)-7-methoxy-2-phenyl-3,4-dihydro-2H-1-benzopyran)chromium(0)], [Cr(C(16)H(16)O(2))(CO)(3)], the Cr(CO)(3) unit is coordinated by the phenyl­ene ring of the flavan ligand, exhibiting a three-legged piano-stool conformation, with a point to plane distance of 1.750 (1) Å. The phenyl ring is twisted away from the fused ring system by 36.49 (5)° (r.m.s. deviation = 0.027 Å; fitted atoms are the C(6) ring and the attached fused-ring C and O atoms). The dihydro­pyran ring displays a distorted envelope configuration by displacement of the phenyl-bearing and the adjacent ring C atoms from the fused-ring system plane by 0.356 (2) and 0.402 (2) Å, respectively. International Union of Crystallography 2010-07-10 /pmc/articles/PMC3007425/ /pubmed/21588147 http://dx.doi.org/10.1107/S1600536810024992 Text en © Tonder et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
van Tonder, Johannes. H.
Bezuidenhoudt, Barend C. B.
Janse van Rensburg, J. Marthinus
Racemic tricarbon­yl(η(6)-7-meth­oxy­flavan)chromium(0)
title Racemic tricarbon­yl(η(6)-7-meth­oxy­flavan)chromium(0)
title_full Racemic tricarbon­yl(η(6)-7-meth­oxy­flavan)chromium(0)
title_fullStr Racemic tricarbon­yl(η(6)-7-meth­oxy­flavan)chromium(0)
title_full_unstemmed Racemic tricarbon­yl(η(6)-7-meth­oxy­flavan)chromium(0)
title_short Racemic tricarbon­yl(η(6)-7-meth­oxy­flavan)chromium(0)
title_sort racemic tricarbon­yl(η(6)-7-meth­oxy­flavan)chromium(0)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007425/
https://www.ncbi.nlm.nih.gov/pubmed/21588147
http://dx.doi.org/10.1107/S1600536810024992
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