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Racemic tricarbonyl(η(6)-7-methoxyflavan)chromium(0)
In the title compound [systematic name: tricarbonyl(η(6)-7-methoxy-2-phenyl-3,4-dihydro-2H-1-benzopyran)chromium(0)], [Cr(C(16)H(16)O(2))(CO)(3)], the Cr(CO)(3) unit is coordinated by the phenylene ring of the flavan ligand, exhibiting a three-legged piano-stool conformation, with a point to plane...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007425/ https://www.ncbi.nlm.nih.gov/pubmed/21588147 http://dx.doi.org/10.1107/S1600536810024992 |
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author | van Tonder, Johannes. H. Bezuidenhoudt, Barend C. B. Janse van Rensburg, J. Marthinus |
author_facet | van Tonder, Johannes. H. Bezuidenhoudt, Barend C. B. Janse van Rensburg, J. Marthinus |
author_sort | van Tonder, Johannes. H. |
collection | PubMed |
description | In the title compound [systematic name: tricarbonyl(η(6)-7-methoxy-2-phenyl-3,4-dihydro-2H-1-benzopyran)chromium(0)], [Cr(C(16)H(16)O(2))(CO)(3)], the Cr(CO)(3) unit is coordinated by the phenylene ring of the flavan ligand, exhibiting a three-legged piano-stool conformation, with a point to plane distance of 1.750 (1) Å. The phenyl ring is twisted away from the fused ring system by 36.49 (5)° (r.m.s. deviation = 0.027 Å; fitted atoms are the C(6) ring and the attached fused-ring C and O atoms). The dihydropyran ring displays a distorted envelope configuration by displacement of the phenyl-bearing and the adjacent ring C atoms from the fused-ring system plane by 0.356 (2) and 0.402 (2) Å, respectively. |
format | Text |
id | pubmed-3007425 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30074252010-12-30 Racemic tricarbonyl(η(6)-7-methoxyflavan)chromium(0) van Tonder, Johannes. H. Bezuidenhoudt, Barend C. B. Janse van Rensburg, J. Marthinus Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound [systematic name: tricarbonyl(η(6)-7-methoxy-2-phenyl-3,4-dihydro-2H-1-benzopyran)chromium(0)], [Cr(C(16)H(16)O(2))(CO)(3)], the Cr(CO)(3) unit is coordinated by the phenylene ring of the flavan ligand, exhibiting a three-legged piano-stool conformation, with a point to plane distance of 1.750 (1) Å. The phenyl ring is twisted away from the fused ring system by 36.49 (5)° (r.m.s. deviation = 0.027 Å; fitted atoms are the C(6) ring and the attached fused-ring C and O atoms). The dihydropyran ring displays a distorted envelope configuration by displacement of the phenyl-bearing and the adjacent ring C atoms from the fused-ring system plane by 0.356 (2) and 0.402 (2) Å, respectively. International Union of Crystallography 2010-07-10 /pmc/articles/PMC3007425/ /pubmed/21588147 http://dx.doi.org/10.1107/S1600536810024992 Text en © Tonder et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers van Tonder, Johannes. H. Bezuidenhoudt, Barend C. B. Janse van Rensburg, J. Marthinus Racemic tricarbonyl(η(6)-7-methoxyflavan)chromium(0) |
title | Racemic tricarbonyl(η(6)-7-methoxyflavan)chromium(0) |
title_full | Racemic tricarbonyl(η(6)-7-methoxyflavan)chromium(0) |
title_fullStr | Racemic tricarbonyl(η(6)-7-methoxyflavan)chromium(0) |
title_full_unstemmed | Racemic tricarbonyl(η(6)-7-methoxyflavan)chromium(0) |
title_short | Racemic tricarbonyl(η(6)-7-methoxyflavan)chromium(0) |
title_sort | racemic tricarbonyl(η(6)-7-methoxyflavan)chromium(0) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007425/ https://www.ncbi.nlm.nih.gov/pubmed/21588147 http://dx.doi.org/10.1107/S1600536810024992 |
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