1,4,8,11-Tetra­azoniacyclo­tetra­decane tetra­chloridocobaltate(II) dichloride

The asymmetric unit of the title compound, (C(10)H(28)N(4))[CoCl(4)]Cl(2), contains two half-mol­ecules of the macrocycle, which are both completed by crystallographic inversion symmetry. In the dianion, the Co(2+) cation is tetra­hedrally coordinated by four Cl atoms; the Co—Cl bond lengths correla...

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Detalles Bibliográficos
Autores principales: Ferchichi, Tarek, Trojett, Besma, Dhaouadi, Hassouna, Marouani, Houda
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007426/
https://www.ncbi.nlm.nih.gov/pubmed/21588118
http://dx.doi.org/10.1107/S1600536810025079
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author Ferchichi, Tarek
Trojett, Besma
Dhaouadi, Hassouna
Marouani, Houda
author_facet Ferchichi, Tarek
Trojett, Besma
Dhaouadi, Hassouna
Marouani, Houda
author_sort Ferchichi, Tarek
collection PubMed
description The asymmetric unit of the title compound, (C(10)H(28)N(4))[CoCl(4)]Cl(2), contains two half-mol­ecules of the macrocycle, which are both completed by crystallographic inversion symmetry. In the dianion, the Co(2+) cation is tetra­hedrally coordinated by four Cl atoms; the Co—Cl bond lengths correlate with the number of hydrogen bonds that the chloride ions accept. The crystal cohesion is supported by electrostatic inter­actions which, together with numerous N—H⋯Cl, N—H⋯(Cl,Cl) and C—H⋯Cl hydrogen bonds, lead to a three-dimensional network.
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spelling pubmed-30074262010-12-30 1,4,8,11-Tetra­azoniacyclo­tetra­decane tetra­chloridocobaltate(II) dichloride Ferchichi, Tarek Trojett, Besma Dhaouadi, Hassouna Marouani, Houda Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(10)H(28)N(4))[CoCl(4)]Cl(2), contains two half-mol­ecules of the macrocycle, which are both completed by crystallographic inversion symmetry. In the dianion, the Co(2+) cation is tetra­hedrally coordinated by four Cl atoms; the Co—Cl bond lengths correlate with the number of hydrogen bonds that the chloride ions accept. The crystal cohesion is supported by electrostatic inter­actions which, together with numerous N—H⋯Cl, N—H⋯(Cl,Cl) and C—H⋯Cl hydrogen bonds, lead to a three-dimensional network. International Union of Crystallography 2010-07-03 /pmc/articles/PMC3007426/ /pubmed/21588118 http://dx.doi.org/10.1107/S1600536810025079 Text en © Ferchichi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ferchichi, Tarek
Trojett, Besma
Dhaouadi, Hassouna
Marouani, Houda
1,4,8,11-Tetra­azoniacyclo­tetra­decane tetra­chloridocobaltate(II) dichloride
title 1,4,8,11-Tetra­azoniacyclo­tetra­decane tetra­chloridocobaltate(II) dichloride
title_full 1,4,8,11-Tetra­azoniacyclo­tetra­decane tetra­chloridocobaltate(II) dichloride
title_fullStr 1,4,8,11-Tetra­azoniacyclo­tetra­decane tetra­chloridocobaltate(II) dichloride
title_full_unstemmed 1,4,8,11-Tetra­azoniacyclo­tetra­decane tetra­chloridocobaltate(II) dichloride
title_short 1,4,8,11-Tetra­azoniacyclo­tetra­decane tetra­chloridocobaltate(II) dichloride
title_sort 1,4,8,11-tetra­azoniacyclo­tetra­decane tetra­chloridocobaltate(ii) dichloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007426/
https://www.ncbi.nlm.nih.gov/pubmed/21588118
http://dx.doi.org/10.1107/S1600536810025079
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AT dhaouadihassouna 14811tetraazoniacyclotetradecanetetrachloridocobaltateiidichloride
AT marouanihouda 14811tetraazoniacyclotetradecanetetrachloridocobaltateiidichloride

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