[(1R,4S)-(+)-3-Benzoyl-1,7,7-trimethyl­bicyclo­[2.2.1]heptan-2-olato-κ(2) O (2),O (3)](η(4)-norbornadiene)rhodium(I)

In the title complex mol­ecule, [Rh(C(17)H(19)O(2))(C(7)H(8))], the rhodium(I) metal centre is coordinated by the O atoms of a benzoyl­camphorate anion and the C=C bonds of the norbornadiene mol­ecule into a slightly distorted square-planar coordination geometry. The six-membered chelate ring is ess...

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Detalles Bibliográficos
Autores principales: Harrad, Mohamed Anoir, Boualy, Brahim, Ali, Mustapha Ait, Firdoussi, Larbi El, Rizzoli, Corrado
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007428/
https://www.ncbi.nlm.nih.gov/pubmed/21588153
http://dx.doi.org/10.1107/S160053681002667X
Descripción
Sumario:In the title complex mol­ecule, [Rh(C(17)H(19)O(2))(C(7)H(8))], the rhodium(I) metal centre is coordinated by the O atoms of a benzoyl­camphorate anion and the C=C bonds of the norbornadiene mol­ecule into a slightly distorted square-planar coordination geometry. The six-membered chelate ring is essentially planar (r.m.s. deviation = 0.0378 Å) and forms a dihedral angle of 31.67 (11)° with the phenyl ring.

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