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[(1R,4S)-(+)-3-Benzoyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-olato-κ(2) O (2),O (3)](η(4)-norbornadiene)rhodium(I)
In the title complex molecule, [Rh(C(17)H(19)O(2))(C(7)H(8))], the rhodium(I) metal centre is coordinated by the O atoms of a benzoylcamphorate anion and the C=C bonds of the norbornadiene molecule into a slightly distorted square-planar coordination geometry. The six-membered chelate ring is ess...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007428/ https://www.ncbi.nlm.nih.gov/pubmed/21588153 http://dx.doi.org/10.1107/S160053681002667X |
| _version_ | 1782194355456442368 |
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| author | Harrad, Mohamed Anoir Boualy, Brahim Ali, Mustapha Ait Firdoussi, Larbi El Rizzoli, Corrado |
| author_facet | Harrad, Mohamed Anoir Boualy, Brahim Ali, Mustapha Ait Firdoussi, Larbi El Rizzoli, Corrado |
| author_sort | Harrad, Mohamed Anoir |
| collection | PubMed |
| description | In the title complex molecule, [Rh(C(17)H(19)O(2))(C(7)H(8))], the rhodium(I) metal centre is coordinated by the O atoms of a benzoylcamphorate anion and the C=C bonds of the norbornadiene molecule into a slightly distorted square-planar coordination geometry. The six-membered chelate ring is essentially planar (r.m.s. deviation = 0.0378 Å) and forms a dihedral angle of 31.67 (11)° with the phenyl ring. |
| format | Text |
| id | pubmed-3007428 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30074282010-12-30 [(1R,4S)-(+)-3-Benzoyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-olato-κ(2) O (2),O (3)](η(4)-norbornadiene)rhodium(I) Harrad, Mohamed Anoir Boualy, Brahim Ali, Mustapha Ait Firdoussi, Larbi El Rizzoli, Corrado Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex molecule, [Rh(C(17)H(19)O(2))(C(7)H(8))], the rhodium(I) metal centre is coordinated by the O atoms of a benzoylcamphorate anion and the C=C bonds of the norbornadiene molecule into a slightly distorted square-planar coordination geometry. The six-membered chelate ring is essentially planar (r.m.s. deviation = 0.0378 Å) and forms a dihedral angle of 31.67 (11)° with the phenyl ring. International Union of Crystallography 2010-07-10 /pmc/articles/PMC3007428/ /pubmed/21588153 http://dx.doi.org/10.1107/S160053681002667X Text en © Harrad et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Harrad, Mohamed Anoir Boualy, Brahim Ali, Mustapha Ait Firdoussi, Larbi El Rizzoli, Corrado [(1R,4S)-(+)-3-Benzoyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-olato-κ(2) O (2),O (3)](η(4)-norbornadiene)rhodium(I) |
| title | [(1R,4S)-(+)-3-Benzoyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-olato-κ(2)
O
(2),O
(3)](η(4)-norbornadiene)rhodium(I) |
| title_full | [(1R,4S)-(+)-3-Benzoyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-olato-κ(2)
O
(2),O
(3)](η(4)-norbornadiene)rhodium(I) |
| title_fullStr | [(1R,4S)-(+)-3-Benzoyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-olato-κ(2)
O
(2),O
(3)](η(4)-norbornadiene)rhodium(I) |
| title_full_unstemmed | [(1R,4S)-(+)-3-Benzoyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-olato-κ(2)
O
(2),O
(3)](η(4)-norbornadiene)rhodium(I) |
| title_short | [(1R,4S)-(+)-3-Benzoyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-olato-κ(2)
O
(2),O
(3)](η(4)-norbornadiene)rhodium(I) |
| title_sort | [(1r,4s)-(+)-3-benzoyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-olato-κ(2)
o
(2),o
(3)](η(4)-norbornadiene)rhodium(i) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007428/ https://www.ncbi.nlm.nih.gov/pubmed/21588153 http://dx.doi.org/10.1107/S160053681002667X |
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