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Bis[(3-chlorobenzyl)ammonium] 2-phenylpropanedioate dihydrate
In the asymmetric unit of the title compound, 2C(7)H(9)ClN(+)·C(9)H(6)O(4) (2−)·2H(2)O, there are two crystallographically independent cations, one dianion and two water molecules. The dihedral angle between the two carboxylate groups of the dianion is 78.1 (2)°. In the crystal, the components are...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007429/ https://www.ncbi.nlm.nih.gov/pubmed/21588449 http://dx.doi.org/10.1107/S1600536810029764 |
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author | Harrison, Jerry Joe Ebow Kingsley Kingsford-Adaboh, Robert Gotoh, Kazuma Ishida, Hiroyuki |
author_facet | Harrison, Jerry Joe Ebow Kingsley Kingsford-Adaboh, Robert Gotoh, Kazuma Ishida, Hiroyuki |
author_sort | Harrison, Jerry Joe Ebow Kingsley |
collection | PubMed |
description | In the asymmetric unit of the title compound, 2C(7)H(9)ClN(+)·C(9)H(6)O(4) (2−)·2H(2)O, there are two crystallographically independent cations, one dianion and two water molecules. The dihedral angle between the two carboxylate groups of the dianion is 78.1 (2)°. In the crystal, the components are held together by N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds, forming a layer parallel to the bc plane, with the hydrophilic and hydrophobic groups located in the inner and outer regions of the layers, respectively. |
format | Text |
id | pubmed-3007429 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30074292010-12-30 Bis[(3-chlorobenzyl)ammonium] 2-phenylpropanedioate dihydrate Harrison, Jerry Joe Ebow Kingsley Kingsford-Adaboh, Robert Gotoh, Kazuma Ishida, Hiroyuki Acta Crystallogr Sect E Struct Rep Online Organic Papers In the asymmetric unit of the title compound, 2C(7)H(9)ClN(+)·C(9)H(6)O(4) (2−)·2H(2)O, there are two crystallographically independent cations, one dianion and two water molecules. The dihedral angle between the two carboxylate groups of the dianion is 78.1 (2)°. In the crystal, the components are held together by N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds, forming a layer parallel to the bc plane, with the hydrophilic and hydrophobic groups located in the inner and outer regions of the layers, respectively. International Union of Crystallography 2010-07-31 /pmc/articles/PMC3007429/ /pubmed/21588449 http://dx.doi.org/10.1107/S1600536810029764 Text en © Harrison et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Harrison, Jerry Joe Ebow Kingsley Kingsford-Adaboh, Robert Gotoh, Kazuma Ishida, Hiroyuki Bis[(3-chlorobenzyl)ammonium] 2-phenylpropanedioate dihydrate |
title | Bis[(3-chlorobenzyl)ammonium] 2-phenylpropanedioate dihydrate |
title_full | Bis[(3-chlorobenzyl)ammonium] 2-phenylpropanedioate dihydrate |
title_fullStr | Bis[(3-chlorobenzyl)ammonium] 2-phenylpropanedioate dihydrate |
title_full_unstemmed | Bis[(3-chlorobenzyl)ammonium] 2-phenylpropanedioate dihydrate |
title_short | Bis[(3-chlorobenzyl)ammonium] 2-phenylpropanedioate dihydrate |
title_sort | bis[(3-chlorobenzyl)ammonium] 2-phenylpropanedioate dihydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007429/ https://www.ncbi.nlm.nih.gov/pubmed/21588449 http://dx.doi.org/10.1107/S1600536810029764 |
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