Poly[bis­[μ-1,4-bis­(1,2,4-triazol-1-ylmeth­yl)benzene-κ(2) N (4):N (4′)]dichloridomanganese(II)]

The Mn(II) atom in the title coordination polymer, [MnCl(2)(C(12)H(12)N(6))(2)](n), lies on a center of inversion in a six-coordinate octa­hedral environment comprising four N-atom donors from four N-heterocyclic ligands and two chloride atoms. Bridging by the ligands results in a layer structure of...

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Detalles Bibliográficos
Autores principales: Ding, Bin, Zou, Hong-Ai
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007432/
https://www.ncbi.nlm.nih.gov/pubmed/21588164
http://dx.doi.org/10.1107/S1600536810026322
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author Ding, Bin
Zou, Hong-Ai
author_facet Ding, Bin
Zou, Hong-Ai
author_sort Ding, Bin
collection PubMed
description The Mn(II) atom in the title coordination polymer, [MnCl(2)(C(12)H(12)N(6))(2)](n), lies on a center of inversion in a six-coordinate octa­hedral environment comprising four N-atom donors from four N-heterocyclic ligands and two chloride atoms. Bridging by the ligands results in a layer structure of a 14.79 (5) × 14.79 (5) Å (4,4) rhombic net topology, with the Mn(II) atoms all lying on a plane. The parallel layers stack in an ABCABC… manner through inter­layer C—H⋯N and C—H⋯Cl hydrogen bonds.
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spelling pubmed-30074322010-12-30 Poly[bis­[μ-1,4-bis­(1,2,4-triazol-1-ylmeth­yl)benzene-κ(2) N (4):N (4′)]dichloridomanganese(II)] Ding, Bin Zou, Hong-Ai Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Mn(II) atom in the title coordination polymer, [MnCl(2)(C(12)H(12)N(6))(2)](n), lies on a center of inversion in a six-coordinate octa­hedral environment comprising four N-atom donors from four N-heterocyclic ligands and two chloride atoms. Bridging by the ligands results in a layer structure of a 14.79 (5) × 14.79 (5) Å (4,4) rhombic net topology, with the Mn(II) atoms all lying on a plane. The parallel layers stack in an ABCABC… manner through inter­layer C—H⋯N and C—H⋯Cl hydrogen bonds. International Union of Crystallography 2010-07-14 /pmc/articles/PMC3007432/ /pubmed/21588164 http://dx.doi.org/10.1107/S1600536810026322 Text en © Ding and Zou 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ding, Bin
Zou, Hong-Ai
Poly[bis­[μ-1,4-bis­(1,2,4-triazol-1-ylmeth­yl)benzene-κ(2) N (4):N (4′)]dichloridomanganese(II)]
title Poly[bis­[μ-1,4-bis­(1,2,4-triazol-1-ylmeth­yl)benzene-κ(2) N (4):N (4′)]dichloridomanganese(II)]
title_full Poly[bis­[μ-1,4-bis­(1,2,4-triazol-1-ylmeth­yl)benzene-κ(2) N (4):N (4′)]dichloridomanganese(II)]
title_fullStr Poly[bis­[μ-1,4-bis­(1,2,4-triazol-1-ylmeth­yl)benzene-κ(2) N (4):N (4′)]dichloridomanganese(II)]
title_full_unstemmed Poly[bis­[μ-1,4-bis­(1,2,4-triazol-1-ylmeth­yl)benzene-κ(2) N (4):N (4′)]dichloridomanganese(II)]
title_short Poly[bis­[μ-1,4-bis­(1,2,4-triazol-1-ylmeth­yl)benzene-κ(2) N (4):N (4′)]dichloridomanganese(II)]
title_sort poly[bis­[μ-1,4-bis­(1,2,4-triazol-1-ylmeth­yl)benzene-κ(2) n (4):n (4′)]dichloridomanganese(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007432/
https://www.ncbi.nlm.nih.gov/pubmed/21588164
http://dx.doi.org/10.1107/S1600536810026322
work_keys_str_mv AT dingbin polybism14bis124triazol1ylmethylbenzenek2n4n4dichloridomanganeseii
AT zouhongai polybism14bis124triazol1ylmethylbenzenek2n4n4dichloridomanganeseii

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