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(2Z)-2-[(2,3-Dimethyl­phen­yl)imino]-1,2-diphenyl­ethanone

In the title compound, C(22)H(19)NO, the 2,3-dimethyl­anilinic group is planar with an r.m.s. deviation of 0.0226 Å. The phenyl rings with the carbonyl and imine substituents are also planar with r.m.s. deviations of 0.0019 and 0.0048 Å, respectively. These phenyl rings are oriented at dihedral angl...

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Autores principales: Tariq, Muhammad Ilyas, Sarfraz, Muhammad, Tahir, M. Nawaz, Ahmad, Shahbaz, Hussain, Ishtiaq
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007434/
https://www.ncbi.nlm.nih.gov/pubmed/21588378
http://dx.doi.org/10.1107/S1600536810028217
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author Tariq, Muhammad Ilyas
Sarfraz, Muhammad
Tahir, M. Nawaz
Ahmad, Shahbaz
Hussain, Ishtiaq
author_facet Tariq, Muhammad Ilyas
Sarfraz, Muhammad
Tahir, M. Nawaz
Ahmad, Shahbaz
Hussain, Ishtiaq
author_sort Tariq, Muhammad Ilyas
collection PubMed
description In the title compound, C(22)H(19)NO, the 2,3-dimethyl­anilinic group is planar with an r.m.s. deviation of 0.0226 Å. The phenyl rings with the carbonyl and imine substituents are also planar with r.m.s. deviations of 0.0019 and 0.0048 Å, respectively. These phenyl rings are oriented at dihedral angles of 74.70 (5) and 79.43 (5)°, respectively, with the 2,3-dimethyl­anilinic group, whereas the dihedral angle between them is 88.28 (4)°. Weak intra­molecular C—H⋯N hydrogen bonding occurs and completes an S(5) ring motif in the mol­ecule. In the crystal, weak π–π inter­actions are present between the carbonyl-containing phenyl rings at a centroid–centroid distance of 3.5958 (12) Å. C—H⋯π inter­actions between the 2,3-dimethyl­anilinic and the carbonyl-containing phenyl rings are also present, where the C—H group is from the former.
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spelling pubmed-30074342010-12-30 (2Z)-2-[(2,3-Dimethyl­phen­yl)imino]-1,2-diphenyl­ethanone Tariq, Muhammad Ilyas Sarfraz, Muhammad Tahir, M. Nawaz Ahmad, Shahbaz Hussain, Ishtiaq Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(22)H(19)NO, the 2,3-dimethyl­anilinic group is planar with an r.m.s. deviation of 0.0226 Å. The phenyl rings with the carbonyl and imine substituents are also planar with r.m.s. deviations of 0.0019 and 0.0048 Å, respectively. These phenyl rings are oriented at dihedral angles of 74.70 (5) and 79.43 (5)°, respectively, with the 2,3-dimethyl­anilinic group, whereas the dihedral angle between them is 88.28 (4)°. Weak intra­molecular C—H⋯N hydrogen bonding occurs and completes an S(5) ring motif in the mol­ecule. In the crystal, weak π–π inter­actions are present between the carbonyl-containing phenyl rings at a centroid–centroid distance of 3.5958 (12) Å. C—H⋯π inter­actions between the 2,3-dimethyl­anilinic and the carbonyl-containing phenyl rings are also present, where the C—H group is from the former. International Union of Crystallography 2010-07-21 /pmc/articles/PMC3007434/ /pubmed/21588378 http://dx.doi.org/10.1107/S1600536810028217 Text en © Tariq et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tariq, Muhammad Ilyas
Sarfraz, Muhammad
Tahir, M. Nawaz
Ahmad, Shahbaz
Hussain, Ishtiaq
(2Z)-2-[(2,3-Dimethyl­phen­yl)imino]-1,2-diphenyl­ethanone
title (2Z)-2-[(2,3-Dimethyl­phen­yl)imino]-1,2-diphenyl­ethanone
title_full (2Z)-2-[(2,3-Dimethyl­phen­yl)imino]-1,2-diphenyl­ethanone
title_fullStr (2Z)-2-[(2,3-Dimethyl­phen­yl)imino]-1,2-diphenyl­ethanone
title_full_unstemmed (2Z)-2-[(2,3-Dimethyl­phen­yl)imino]-1,2-diphenyl­ethanone
title_short (2Z)-2-[(2,3-Dimethyl­phen­yl)imino]-1,2-diphenyl­ethanone
title_sort (2z)-2-[(2,3-dimethyl­phen­yl)imino]-1,2-diphenyl­ethanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007434/
https://www.ncbi.nlm.nih.gov/pubmed/21588378
http://dx.doi.org/10.1107/S1600536810028217
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