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(2Z)-2-[(2,3-Dimethylphenyl)imino]-1,2-diphenylethanone
In the title compound, C(22)H(19)NO, the 2,3-dimethylanilinic group is planar with an r.m.s. deviation of 0.0226 Å. The phenyl rings with the carbonyl and imine substituents are also planar with r.m.s. deviations of 0.0019 and 0.0048 Å, respectively. These phenyl rings are oriented at dihedral angl...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007434/ https://www.ncbi.nlm.nih.gov/pubmed/21588378 http://dx.doi.org/10.1107/S1600536810028217 |
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author | Tariq, Muhammad Ilyas Sarfraz, Muhammad Tahir, M. Nawaz Ahmad, Shahbaz Hussain, Ishtiaq |
author_facet | Tariq, Muhammad Ilyas Sarfraz, Muhammad Tahir, M. Nawaz Ahmad, Shahbaz Hussain, Ishtiaq |
author_sort | Tariq, Muhammad Ilyas |
collection | PubMed |
description | In the title compound, C(22)H(19)NO, the 2,3-dimethylanilinic group is planar with an r.m.s. deviation of 0.0226 Å. The phenyl rings with the carbonyl and imine substituents are also planar with r.m.s. deviations of 0.0019 and 0.0048 Å, respectively. These phenyl rings are oriented at dihedral angles of 74.70 (5) and 79.43 (5)°, respectively, with the 2,3-dimethylanilinic group, whereas the dihedral angle between them is 88.28 (4)°. Weak intramolecular C—H⋯N hydrogen bonding occurs and completes an S(5) ring motif in the molecule. In the crystal, weak π–π interactions are present between the carbonyl-containing phenyl rings at a centroid–centroid distance of 3.5958 (12) Å. C—H⋯π interactions between the 2,3-dimethylanilinic and the carbonyl-containing phenyl rings are also present, where the C—H group is from the former. |
format | Text |
id | pubmed-3007434 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30074342010-12-30 (2Z)-2-[(2,3-Dimethylphenyl)imino]-1,2-diphenylethanone Tariq, Muhammad Ilyas Sarfraz, Muhammad Tahir, M. Nawaz Ahmad, Shahbaz Hussain, Ishtiaq Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(22)H(19)NO, the 2,3-dimethylanilinic group is planar with an r.m.s. deviation of 0.0226 Å. The phenyl rings with the carbonyl and imine substituents are also planar with r.m.s. deviations of 0.0019 and 0.0048 Å, respectively. These phenyl rings are oriented at dihedral angles of 74.70 (5) and 79.43 (5)°, respectively, with the 2,3-dimethylanilinic group, whereas the dihedral angle between them is 88.28 (4)°. Weak intramolecular C—H⋯N hydrogen bonding occurs and completes an S(5) ring motif in the molecule. In the crystal, weak π–π interactions are present between the carbonyl-containing phenyl rings at a centroid–centroid distance of 3.5958 (12) Å. C—H⋯π interactions between the 2,3-dimethylanilinic and the carbonyl-containing phenyl rings are also present, where the C—H group is from the former. International Union of Crystallography 2010-07-21 /pmc/articles/PMC3007434/ /pubmed/21588378 http://dx.doi.org/10.1107/S1600536810028217 Text en © Tariq et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Tariq, Muhammad Ilyas Sarfraz, Muhammad Tahir, M. Nawaz Ahmad, Shahbaz Hussain, Ishtiaq (2Z)-2-[(2,3-Dimethylphenyl)imino]-1,2-diphenylethanone |
title | (2Z)-2-[(2,3-Dimethylphenyl)imino]-1,2-diphenylethanone |
title_full | (2Z)-2-[(2,3-Dimethylphenyl)imino]-1,2-diphenylethanone |
title_fullStr | (2Z)-2-[(2,3-Dimethylphenyl)imino]-1,2-diphenylethanone |
title_full_unstemmed | (2Z)-2-[(2,3-Dimethylphenyl)imino]-1,2-diphenylethanone |
title_short | (2Z)-2-[(2,3-Dimethylphenyl)imino]-1,2-diphenylethanone |
title_sort | (2z)-2-[(2,3-dimethylphenyl)imino]-1,2-diphenylethanone |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007434/ https://www.ncbi.nlm.nih.gov/pubmed/21588378 http://dx.doi.org/10.1107/S1600536810028217 |
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