Cargando…

[2,3,7,8,13,14,17,18-Octa­kis(ethyl­sulfan­yl)-5,10,15,20-porphyrazinato]zinc(II)

In the title compound, [Zn(C(32)H(40)N(8)S(8))], the Zn(II) ion is coordinated by four N atoms in a slightly distorted square-planar environment. In addition, there is a Zn⋯S contact involving a symmetry-related S atom which, when considered, forms a pseudo-square-pyramidal coordination with respect...

Descripción completa

Detalles Bibliográficos
Autores principales: Akkurt, Mehmet, Coşkun, Naciye Yılmaz, Kılıçaslan, Fatma Aytan, Yalçın, Sabiha Manav, Büyükgüngör, Orhan, Gül, Ahmet
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007436/
https://www.ncbi.nlm.nih.gov/pubmed/21588217
http://dx.doi.org/10.1107/S1600536810028588
_version_ 1782194357416230912
author Akkurt, Mehmet
Coşkun, Naciye Yılmaz
Kılıçaslan, Fatma Aytan
Yalçın, Sabiha Manav
Büyükgüngör, Orhan
Gül, Ahmet
author_facet Akkurt, Mehmet
Coşkun, Naciye Yılmaz
Kılıçaslan, Fatma Aytan
Yalçın, Sabiha Manav
Büyükgüngör, Orhan
Gül, Ahmet
author_sort Akkurt, Mehmet
collection PubMed
description In the title compound, [Zn(C(32)H(40)N(8)S(8))], the Zn(II) ion is coordinated by four N atoms in a slightly distorted square-planar environment. In addition, there is a Zn⋯S contact involving a symmetry-related S atom which, when considered, forms a pseudo-square-pyramidal coordination with respect to the Zn(II) ion. Three of the ethyl groups are disordered over two sites with occupancy ratios of 0.841 (10):0.159 (10), 0.802 (10):0.198 (10) and 0.457 (13):0.543 (13). Weak intra­molecular C—H⋯N and C—H⋯S inter­actions contribute to the stability of the mol­ecular conformation. Inter­molecular C—H⋯S contacts, weak C—H⋯π inter­actions and π–π stacking inter­actions [centroid–centriod distances = 3.832 (4) and 3.850 (5) Å] contribute to the stabilization of the crystal structure.
format Text
id pubmed-3007436
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30074362010-12-30 [2,3,7,8,13,14,17,18-Octa­kis(ethyl­sulfan­yl)-5,10,15,20-porphyrazinato]zinc(II) Akkurt, Mehmet Coşkun, Naciye Yılmaz Kılıçaslan, Fatma Aytan Yalçın, Sabiha Manav Büyükgüngör, Orhan Gül, Ahmet Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(32)H(40)N(8)S(8))], the Zn(II) ion is coordinated by four N atoms in a slightly distorted square-planar environment. In addition, there is a Zn⋯S contact involving a symmetry-related S atom which, when considered, forms a pseudo-square-pyramidal coordination with respect to the Zn(II) ion. Three of the ethyl groups are disordered over two sites with occupancy ratios of 0.841 (10):0.159 (10), 0.802 (10):0.198 (10) and 0.457 (13):0.543 (13). Weak intra­molecular C—H⋯N and C—H⋯S inter­actions contribute to the stability of the mol­ecular conformation. Inter­molecular C—H⋯S contacts, weak C—H⋯π inter­actions and π–π stacking inter­actions [centroid–centriod distances = 3.832 (4) and 3.850 (5) Å] contribute to the stabilization of the crystal structure. International Union of Crystallography 2010-07-24 /pmc/articles/PMC3007436/ /pubmed/21588217 http://dx.doi.org/10.1107/S1600536810028588 Text en © Akkurt et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Akkurt, Mehmet
Coşkun, Naciye Yılmaz
Kılıçaslan, Fatma Aytan
Yalçın, Sabiha Manav
Büyükgüngör, Orhan
Gül, Ahmet
[2,3,7,8,13,14,17,18-Octa­kis(ethyl­sulfan­yl)-5,10,15,20-porphyrazinato]zinc(II)
title [2,3,7,8,13,14,17,18-Octa­kis(ethyl­sulfan­yl)-5,10,15,20-porphyrazinato]zinc(II)
title_full [2,3,7,8,13,14,17,18-Octa­kis(ethyl­sulfan­yl)-5,10,15,20-porphyrazinato]zinc(II)
title_fullStr [2,3,7,8,13,14,17,18-Octa­kis(ethyl­sulfan­yl)-5,10,15,20-porphyrazinato]zinc(II)
title_full_unstemmed [2,3,7,8,13,14,17,18-Octa­kis(ethyl­sulfan­yl)-5,10,15,20-porphyrazinato]zinc(II)
title_short [2,3,7,8,13,14,17,18-Octa­kis(ethyl­sulfan­yl)-5,10,15,20-porphyrazinato]zinc(II)
title_sort [2,3,7,8,13,14,17,18-octa­kis(ethyl­sulfan­yl)-5,10,15,20-porphyrazinato]zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007436/
https://www.ncbi.nlm.nih.gov/pubmed/21588217
http://dx.doi.org/10.1107/S1600536810028588
work_keys_str_mv AT akkurtmehmet 237813141718octakisethylsulfanyl5101520porphyrazinatozincii
AT coskunnaciyeyılmaz 237813141718octakisethylsulfanyl5101520porphyrazinatozincii
AT kılıcaslanfatmaaytan 237813141718octakisethylsulfanyl5101520porphyrazinatozincii
AT yalcınsabihamanav 237813141718octakisethylsulfanyl5101520porphyrazinatozincii
AT buyukgungororhan 237813141718octakisethylsulfanyl5101520porphyrazinatozincii
AT gulahmet 237813141718octakisethylsulfanyl5101520porphyrazinatozincii