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[2,3,7,8,13,14,17,18-Octakis(ethylsulfanyl)-5,10,15,20-porphyrazinato]zinc(II)
In the title compound, [Zn(C(32)H(40)N(8)S(8))], the Zn(II) ion is coordinated by four N atoms in a slightly distorted square-planar environment. In addition, there is a Zn⋯S contact involving a symmetry-related S atom which, when considered, forms a pseudo-square-pyramidal coordination with respect...
Autores principales: | , , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007436/ https://www.ncbi.nlm.nih.gov/pubmed/21588217 http://dx.doi.org/10.1107/S1600536810028588 |
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author | Akkurt, Mehmet Coşkun, Naciye Yılmaz Kılıçaslan, Fatma Aytan Yalçın, Sabiha Manav Büyükgüngör, Orhan Gül, Ahmet |
author_facet | Akkurt, Mehmet Coşkun, Naciye Yılmaz Kılıçaslan, Fatma Aytan Yalçın, Sabiha Manav Büyükgüngör, Orhan Gül, Ahmet |
author_sort | Akkurt, Mehmet |
collection | PubMed |
description | In the title compound, [Zn(C(32)H(40)N(8)S(8))], the Zn(II) ion is coordinated by four N atoms in a slightly distorted square-planar environment. In addition, there is a Zn⋯S contact involving a symmetry-related S atom which, when considered, forms a pseudo-square-pyramidal coordination with respect to the Zn(II) ion. Three of the ethyl groups are disordered over two sites with occupancy ratios of 0.841 (10):0.159 (10), 0.802 (10):0.198 (10) and 0.457 (13):0.543 (13). Weak intramolecular C—H⋯N and C—H⋯S interactions contribute to the stability of the molecular conformation. Intermolecular C—H⋯S contacts, weak C—H⋯π interactions and π–π stacking interactions [centroid–centriod distances = 3.832 (4) and 3.850 (5) Å] contribute to the stabilization of the crystal structure. |
format | Text |
id | pubmed-3007436 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30074362010-12-30 [2,3,7,8,13,14,17,18-Octakis(ethylsulfanyl)-5,10,15,20-porphyrazinato]zinc(II) Akkurt, Mehmet Coşkun, Naciye Yılmaz Kılıçaslan, Fatma Aytan Yalçın, Sabiha Manav Büyükgüngör, Orhan Gül, Ahmet Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(32)H(40)N(8)S(8))], the Zn(II) ion is coordinated by four N atoms in a slightly distorted square-planar environment. In addition, there is a Zn⋯S contact involving a symmetry-related S atom which, when considered, forms a pseudo-square-pyramidal coordination with respect to the Zn(II) ion. Three of the ethyl groups are disordered over two sites with occupancy ratios of 0.841 (10):0.159 (10), 0.802 (10):0.198 (10) and 0.457 (13):0.543 (13). Weak intramolecular C—H⋯N and C—H⋯S interactions contribute to the stability of the molecular conformation. Intermolecular C—H⋯S contacts, weak C—H⋯π interactions and π–π stacking interactions [centroid–centriod distances = 3.832 (4) and 3.850 (5) Å] contribute to the stabilization of the crystal structure. International Union of Crystallography 2010-07-24 /pmc/articles/PMC3007436/ /pubmed/21588217 http://dx.doi.org/10.1107/S1600536810028588 Text en © Akkurt et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Akkurt, Mehmet Coşkun, Naciye Yılmaz Kılıçaslan, Fatma Aytan Yalçın, Sabiha Manav Büyükgüngör, Orhan Gül, Ahmet [2,3,7,8,13,14,17,18-Octakis(ethylsulfanyl)-5,10,15,20-porphyrazinato]zinc(II) |
title | [2,3,7,8,13,14,17,18-Octakis(ethylsulfanyl)-5,10,15,20-porphyrazinato]zinc(II) |
title_full | [2,3,7,8,13,14,17,18-Octakis(ethylsulfanyl)-5,10,15,20-porphyrazinato]zinc(II) |
title_fullStr | [2,3,7,8,13,14,17,18-Octakis(ethylsulfanyl)-5,10,15,20-porphyrazinato]zinc(II) |
title_full_unstemmed | [2,3,7,8,13,14,17,18-Octakis(ethylsulfanyl)-5,10,15,20-porphyrazinato]zinc(II) |
title_short | [2,3,7,8,13,14,17,18-Octakis(ethylsulfanyl)-5,10,15,20-porphyrazinato]zinc(II) |
title_sort | [2,3,7,8,13,14,17,18-octakis(ethylsulfanyl)-5,10,15,20-porphyrazinato]zinc(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007436/ https://www.ncbi.nlm.nih.gov/pubmed/21588217 http://dx.doi.org/10.1107/S1600536810028588 |
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