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4-Nitro-6-[(8-quinolyl­amino)­methyl­idene]cyclo­hexa-2,4-dien-1-one

The mol­ecule of the title compound, C(16)H(11)N(3)O(3), exists in the keto form and the C=O and N—H bonds are mutually cis in the crystal structure. There are two crystallographically independent mol­ecules per asymmetric unit with broadly similar structural data. The only noticeable difference bet...

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Detalles Bibliográficos
Autores principales: Shibahara, Takashi, Takano, Kentaro, Takahashi, Masayuki, Yamasaki, Mikio
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007437/
https://www.ncbi.nlm.nih.gov/pubmed/21588227
http://dx.doi.org/10.1107/S1600536810025250
Descripción
Sumario:The mol­ecule of the title compound, C(16)H(11)N(3)O(3), exists in the keto form and the C=O and N—H bonds are mutually cis in the crystal structure. There are two crystallographically independent mol­ecules per asymmetric unit with broadly similar structural data. The only noticeable difference between the two is the dihedral angles between the benzene and the quinoline rings: 1.04 (4) and 3.07 (4)°. In the structure, intra­molecular N—H⋯O(carbon­yl) and N—H⋯N(pyridine) hydrogen bonds exist but there is no evidence of formal inter­molecular hydrogen-bonding associations.