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(E)-N′-(5-Bromo-2-hydroxybenzylidene)-3,5-dihydroxybenzohydrazide monohydrate
The Schiff base molecule in the title compound, C(14)H(11)BrN(2)O(4)·H(2)O, is almost planar with an r.m.s. deviation for the non-H atoms of 0.16 Å. In the crystal structure, the Schiff base molecules and the water molecules are linked together by intermolecular N—H⋯O and O—H⋯O hydrogen bonds, l...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007438/ https://www.ncbi.nlm.nih.gov/pubmed/21588352 http://dx.doi.org/10.1107/S1600536810027856 |
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author | Saharin, Siti Munirah Khaledi, Hamid Mohd Ali, Hapipah |
author_facet | Saharin, Siti Munirah Khaledi, Hamid Mohd Ali, Hapipah |
author_sort | Saharin, Siti Munirah |
collection | PubMed |
description | The Schiff base molecule in the title compound, C(14)H(11)BrN(2)O(4)·H(2)O, is almost planar with an r.m.s. deviation for the non-H atoms of 0.16 Å. In the crystal structure, the Schiff base molecules and the water molecules are linked together by intermolecular N—H⋯O and O—H⋯O hydrogen bonds, leading to layers parallel to the bc plane. An intramolecular O—H⋯N hydrogen bond involving the imine N atom and a hydroxy substituent is also observed. |
format | Text |
id | pubmed-3007438 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30074382010-12-30 (E)-N′-(5-Bromo-2-hydroxybenzylidene)-3,5-dihydroxybenzohydrazide monohydrate Saharin, Siti Munirah Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Organic Papers The Schiff base molecule in the title compound, C(14)H(11)BrN(2)O(4)·H(2)O, is almost planar with an r.m.s. deviation for the non-H atoms of 0.16 Å. In the crystal structure, the Schiff base molecules and the water molecules are linked together by intermolecular N—H⋯O and O—H⋯O hydrogen bonds, leading to layers parallel to the bc plane. An intramolecular O—H⋯N hydrogen bond involving the imine N atom and a hydroxy substituent is also observed. International Union of Crystallography 2010-07-17 /pmc/articles/PMC3007438/ /pubmed/21588352 http://dx.doi.org/10.1107/S1600536810027856 Text en © Saharin et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Saharin, Siti Munirah Khaledi, Hamid Mohd Ali, Hapipah (E)-N′-(5-Bromo-2-hydroxybenzylidene)-3,5-dihydroxybenzohydrazide monohydrate |
title | (E)-N′-(5-Bromo-2-hydroxybenzylidene)-3,5-dihydroxybenzohydrazide monohydrate |
title_full | (E)-N′-(5-Bromo-2-hydroxybenzylidene)-3,5-dihydroxybenzohydrazide monohydrate |
title_fullStr | (E)-N′-(5-Bromo-2-hydroxybenzylidene)-3,5-dihydroxybenzohydrazide monohydrate |
title_full_unstemmed | (E)-N′-(5-Bromo-2-hydroxybenzylidene)-3,5-dihydroxybenzohydrazide monohydrate |
title_short | (E)-N′-(5-Bromo-2-hydroxybenzylidene)-3,5-dihydroxybenzohydrazide monohydrate |
title_sort | (e)-n′-(5-bromo-2-hydroxybenzylidene)-3,5-dihydroxybenzohydrazide monohydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007438/ https://www.ncbi.nlm.nih.gov/pubmed/21588352 http://dx.doi.org/10.1107/S1600536810027856 |
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