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(E)-N′-(5-Bromo-2-hy­droxy­benzyl­idene)-3,5-dihy­droxy­benzohydrazide monohydrate

The Schiff base mol­ecule in the title compound, C(14)H(11)BrN(2)O(4)·H(2)O, is almost planar with an r.m.s. deviation for the non-H atoms of 0.16 Å. In the crystal structure, the Schiff base mol­ecules and the water mol­ecules are linked together by inter­molecular N—H⋯O and O—H⋯O hydrogen bonds, l...

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Detalles Bibliográficos
Autores principales: Saharin, Siti Munirah, Khaledi, Hamid, Mohd Ali, Hapipah
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007438/
https://www.ncbi.nlm.nih.gov/pubmed/21588352
http://dx.doi.org/10.1107/S1600536810027856
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author Saharin, Siti Munirah
Khaledi, Hamid
Mohd Ali, Hapipah
author_facet Saharin, Siti Munirah
Khaledi, Hamid
Mohd Ali, Hapipah
author_sort Saharin, Siti Munirah
collection PubMed
description The Schiff base mol­ecule in the title compound, C(14)H(11)BrN(2)O(4)·H(2)O, is almost planar with an r.m.s. deviation for the non-H atoms of 0.16 Å. In the crystal structure, the Schiff base mol­ecules and the water mol­ecules are linked together by inter­molecular N—H⋯O and O—H⋯O hydrogen bonds, leading to layers parallel to the bc plane. An intra­molecular O—H⋯N hydrogen bond involving the imine N atom and a hy­droxy substituent is also observed.
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spelling pubmed-30074382010-12-30 (E)-N′-(5-Bromo-2-hy­droxy­benzyl­idene)-3,5-dihy­droxy­benzohydrazide monohydrate Saharin, Siti Munirah Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Organic Papers The Schiff base mol­ecule in the title compound, C(14)H(11)BrN(2)O(4)·H(2)O, is almost planar with an r.m.s. deviation for the non-H atoms of 0.16 Å. In the crystal structure, the Schiff base mol­ecules and the water mol­ecules are linked together by inter­molecular N—H⋯O and O—H⋯O hydrogen bonds, leading to layers parallel to the bc plane. An intra­molecular O—H⋯N hydrogen bond involving the imine N atom and a hy­droxy substituent is also observed. International Union of Crystallography 2010-07-17 /pmc/articles/PMC3007438/ /pubmed/21588352 http://dx.doi.org/10.1107/S1600536810027856 Text en © Saharin et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Saharin, Siti Munirah
Khaledi, Hamid
Mohd Ali, Hapipah
(E)-N′-(5-Bromo-2-hy­droxy­benzyl­idene)-3,5-dihy­droxy­benzohydrazide monohydrate
title (E)-N′-(5-Bromo-2-hy­droxy­benzyl­idene)-3,5-dihy­droxy­benzohydrazide monohydrate
title_full (E)-N′-(5-Bromo-2-hy­droxy­benzyl­idene)-3,5-dihy­droxy­benzohydrazide monohydrate
title_fullStr (E)-N′-(5-Bromo-2-hy­droxy­benzyl­idene)-3,5-dihy­droxy­benzohydrazide monohydrate
title_full_unstemmed (E)-N′-(5-Bromo-2-hy­droxy­benzyl­idene)-3,5-dihy­droxy­benzohydrazide monohydrate
title_short (E)-N′-(5-Bromo-2-hy­droxy­benzyl­idene)-3,5-dihy­droxy­benzohydrazide monohydrate
title_sort (e)-n′-(5-bromo-2-hy­droxy­benzyl­idene)-3,5-dihy­droxy­benzohydrazide monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007438/
https://www.ncbi.nlm.nih.gov/pubmed/21588352
http://dx.doi.org/10.1107/S1600536810027856
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