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2-Amino-4-methylpyridinium 2-hydroxybenzoate
The asymmetric unit of the title molecular salt, C(6)H(9)N(2) (+)·C(7)H(5)O(3) (−), contains two cations and two anions. Both the salicylate anions contain an intramolecular O—H⋯O hydrogen bond, which generates an S(6) ring. Both the 2-amino-4-methylpyridine molecules are protonated at their pyr...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007449/ https://www.ncbi.nlm.nih.gov/pubmed/21588437 http://dx.doi.org/10.1107/S160053681002965X |
Sumario: | The asymmetric unit of the title molecular salt, C(6)H(9)N(2) (+)·C(7)H(5)O(3) (−), contains two cations and two anions. Both the salicylate anions contain an intramolecular O—H⋯O hydrogen bond, which generates an S(6) ring. Both the 2-amino-4-methylpyridine molecules are protonated at their pyridine N atoms. In the crystal, both cations form two N—H⋯O hydrogen bonds to their adjacent anions, forming ion pairs. Further N—H⋯O links generate sheets lying parallel to the ab plane. In addition, weak C—H⋯O bonds and aromatic π–π stacking interactions [centroid–centroid distances = 3.5691 (9) and 3.6215 (9) Å] are observed between the cations and anions. |
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