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2-Amino-4-methylpyridinium 2-hydroxybenzoate
The asymmetric unit of the title molecular salt, C(6)H(9)N(2) (+)·C(7)H(5)O(3) (−), contains two cations and two anions. Both the salicylate anions contain an intramolecular O—H⋯O hydrogen bond, which generates an S(6) ring. Both the 2-amino-4-methylpyridine molecules are protonated at their pyr...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007449/ https://www.ncbi.nlm.nih.gov/pubmed/21588437 http://dx.doi.org/10.1107/S160053681002965X |
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author | Hemamalini, Madhukar Fun, Hoong-Kun |
author_facet | Hemamalini, Madhukar Fun, Hoong-Kun |
author_sort | Hemamalini, Madhukar |
collection | PubMed |
description | The asymmetric unit of the title molecular salt, C(6)H(9)N(2) (+)·C(7)H(5)O(3) (−), contains two cations and two anions. Both the salicylate anions contain an intramolecular O—H⋯O hydrogen bond, which generates an S(6) ring. Both the 2-amino-4-methylpyridine molecules are protonated at their pyridine N atoms. In the crystal, both cations form two N—H⋯O hydrogen bonds to their adjacent anions, forming ion pairs. Further N—H⋯O links generate sheets lying parallel to the ab plane. In addition, weak C—H⋯O bonds and aromatic π–π stacking interactions [centroid–centroid distances = 3.5691 (9) and 3.6215 (9) Å] are observed between the cations and anions. |
format | Text |
id | pubmed-3007449 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30074492010-12-30 2-Amino-4-methylpyridinium 2-hydroxybenzoate Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title molecular salt, C(6)H(9)N(2) (+)·C(7)H(5)O(3) (−), contains two cations and two anions. Both the salicylate anions contain an intramolecular O—H⋯O hydrogen bond, which generates an S(6) ring. Both the 2-amino-4-methylpyridine molecules are protonated at their pyridine N atoms. In the crystal, both cations form two N—H⋯O hydrogen bonds to their adjacent anions, forming ion pairs. Further N—H⋯O links generate sheets lying parallel to the ab plane. In addition, weak C—H⋯O bonds and aromatic π–π stacking interactions [centroid–centroid distances = 3.5691 (9) and 3.6215 (9) Å] are observed between the cations and anions. International Union of Crystallography 2010-07-31 /pmc/articles/PMC3007449/ /pubmed/21588437 http://dx.doi.org/10.1107/S160053681002965X Text en © Hemamalini and Fun 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Hemamalini, Madhukar Fun, Hoong-Kun 2-Amino-4-methylpyridinium 2-hydroxybenzoate |
title | 2-Amino-4-methylpyridinium 2-hydroxybenzoate |
title_full | 2-Amino-4-methylpyridinium 2-hydroxybenzoate |
title_fullStr | 2-Amino-4-methylpyridinium 2-hydroxybenzoate |
title_full_unstemmed | 2-Amino-4-methylpyridinium 2-hydroxybenzoate |
title_short | 2-Amino-4-methylpyridinium 2-hydroxybenzoate |
title_sort | 2-amino-4-methylpyridinium 2-hydroxybenzoate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007449/ https://www.ncbi.nlm.nih.gov/pubmed/21588437 http://dx.doi.org/10.1107/S160053681002965X |
work_keys_str_mv | AT hemamalinimadhukar 2amino4methylpyridinium2hydroxybenzoate AT funhoongkun 2amino4methylpyridinium2hydroxybenzoate |