(E,E)-1,2-Bis[1-(2-bromo­phen­yl)ethyl­idene]hydrazine

In the title compound, C(16)H(14)Br(2)N(2), the complete molecule is generated by a crystallographic twofold axis. The dihedral angle between the two benzene rings is 35.28 (8)° and that between the best planes of two ethyl­idinehydrazine N—N=C—Me units is 87.67 (11)°. Each of these N/N/C/C planes m...

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Autores principales: Jansrisewangwong, Patcharaporn, Chantrapromma, Suchada, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007455/
https://www.ncbi.nlm.nih.gov/pubmed/21588451
http://dx.doi.org/10.1107/S1600536810029867
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author Jansrisewangwong, Patcharaporn
Chantrapromma, Suchada
Fun, Hoong-Kun
author_facet Jansrisewangwong, Patcharaporn
Chantrapromma, Suchada
Fun, Hoong-Kun
author_sort Jansrisewangwong, Patcharaporn
collection PubMed
description In the title compound, C(16)H(14)Br(2)N(2), the complete molecule is generated by a crystallographic twofold axis. The dihedral angle between the two benzene rings is 35.28 (8)° and that between the best planes of two ethyl­idinehydrazine N—N=C—Me units is 87.67 (11)°. Each of these N/N/C/C planes makes a dihedral angle of 63.81 (10)° with the adjacent benzene ring. In the crystal, the mol­ecules are arranged into a layer parallel to the ac plane through C—H⋯π inter­actions. C⋯Br short contacts [3.4032 (18)–3.5969 (19) Å] are also observed.
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spelling pubmed-30074552010-12-30 (E,E)-1,2-Bis[1-(2-bromo­phen­yl)ethyl­idene]hydrazine Jansrisewangwong, Patcharaporn Chantrapromma, Suchada Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(14)Br(2)N(2), the complete molecule is generated by a crystallographic twofold axis. The dihedral angle between the two benzene rings is 35.28 (8)° and that between the best planes of two ethyl­idinehydrazine N—N=C—Me units is 87.67 (11)°. Each of these N/N/C/C planes makes a dihedral angle of 63.81 (10)° with the adjacent benzene ring. In the crystal, the mol­ecules are arranged into a layer parallel to the ac plane through C—H⋯π inter­actions. C⋯Br short contacts [3.4032 (18)–3.5969 (19) Å] are also observed. International Union of Crystallography 2010-07-31 /pmc/articles/PMC3007455/ /pubmed/21588451 http://dx.doi.org/10.1107/S1600536810029867 Text en © Jansrisewangwong et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jansrisewangwong, Patcharaporn
Chantrapromma, Suchada
Fun, Hoong-Kun
(E,E)-1,2-Bis[1-(2-bromo­phen­yl)ethyl­idene]hydrazine
title (E,E)-1,2-Bis[1-(2-bromo­phen­yl)ethyl­idene]hydrazine
title_full (E,E)-1,2-Bis[1-(2-bromo­phen­yl)ethyl­idene]hydrazine
title_fullStr (E,E)-1,2-Bis[1-(2-bromo­phen­yl)ethyl­idene]hydrazine
title_full_unstemmed (E,E)-1,2-Bis[1-(2-bromo­phen­yl)ethyl­idene]hydrazine
title_short (E,E)-1,2-Bis[1-(2-bromo­phen­yl)ethyl­idene]hydrazine
title_sort (e,e)-1,2-bis[1-(2-bromo­phen­yl)ethyl­idene]hydrazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007455/
https://www.ncbi.nlm.nih.gov/pubmed/21588451
http://dx.doi.org/10.1107/S1600536810029867
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AT chantraprommasuchada ee12bis12bromophenylethylidenehydrazine
AT funhoongkun ee12bis12bromophenylethylidenehydrazine

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