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1-Benzylsulfanyl-2-[(2-chlorophenyl)diazenyl]benzene
The title compound, C(19)H(15)ClN(2)S, a divalent organosulfur compound belonging to the class of ortho-mercaptoazo compounds, is non-ionic in nature. The azo group in the molecule is moved away from the S atom to attain the stable trans-azo configuration. Here the S atom is not electron deficient,...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007467/ https://www.ncbi.nlm.nih.gov/pubmed/21588269 http://dx.doi.org/10.1107/S1600536810025730 |
Sumario: | The title compound, C(19)H(15)ClN(2)S, a divalent organosulfur compound belonging to the class of ortho-mercaptoazo compounds, is non-ionic in nature. The azo group in the molecule is moved away from the S atom to attain the stable trans-azo configuration. Here the S atom is not electron deficient, so no intramolecular N⋯S interaction exists. Due to steric reasons, the molecule is non-planar: the chlorophenyl and benzyl rings are oriented at dihedral angles of 3.21 (8) and 78.18 (5)°, respectively, with respect to the thiophenyl ring. There are no hydrogen bonds and the crystal structure is stabilized by van der Waals interactions. |
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