1-Benzyl­sulfanyl-2-[(2-chloro­phen­yl)diazen­yl]benzene

The title compound, C(19)H(15)ClN(2)S, a divalent organosulfur compound belonging to the class of ortho-mercaptoazo compounds, is non-ionic in nature. The azo group in the mol­ecule is moved away from the S atom to attain the stable trans-azo configuration. Here the S atom is not electron deficient,...

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Detalles Bibliográficos
Autores principales: Barman, Pranjit, Bhattacharjee, Tirtha, Sarma, Rupam
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007467/
https://www.ncbi.nlm.nih.gov/pubmed/21588269
http://dx.doi.org/10.1107/S1600536810025730
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author Barman, Pranjit
Bhattacharjee, Tirtha
Sarma, Rupam
author_facet Barman, Pranjit
Bhattacharjee, Tirtha
Sarma, Rupam
author_sort Barman, Pranjit
collection PubMed
description The title compound, C(19)H(15)ClN(2)S, a divalent organosulfur compound belonging to the class of ortho-mercaptoazo compounds, is non-ionic in nature. The azo group in the mol­ecule is moved away from the S atom to attain the stable trans-azo configuration. Here the S atom is not electron deficient, so no intra­molecular N⋯S inter­action exists. Due to steric reasons, the mol­ecule is non-planar: the chlorophenyl and benzyl rings are oriented at dihedral angles of 3.21 (8) and 78.18 (5)°, respectively, with respect to the thiophenyl ring. There are no hydrogen bonds and the crystal structure is stabilized by van der Waals inter­actions.
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spelling pubmed-30074672010-12-30 1-Benzyl­sulfanyl-2-[(2-chloro­phen­yl)diazen­yl]benzene Barman, Pranjit Bhattacharjee, Tirtha Sarma, Rupam Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(19)H(15)ClN(2)S, a divalent organosulfur compound belonging to the class of ortho-mercaptoazo compounds, is non-ionic in nature. The azo group in the mol­ecule is moved away from the S atom to attain the stable trans-azo configuration. Here the S atom is not electron deficient, so no intra­molecular N⋯S inter­action exists. Due to steric reasons, the mol­ecule is non-planar: the chlorophenyl and benzyl rings are oriented at dihedral angles of 3.21 (8) and 78.18 (5)°, respectively, with respect to the thiophenyl ring. There are no hydrogen bonds and the crystal structure is stabilized by van der Waals inter­actions. International Union of Crystallography 2010-07-07 /pmc/articles/PMC3007467/ /pubmed/21588269 http://dx.doi.org/10.1107/S1600536810025730 Text en © Barman et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Barman, Pranjit
Bhattacharjee, Tirtha
Sarma, Rupam
1-Benzyl­sulfanyl-2-[(2-chloro­phen­yl)diazen­yl]benzene
title 1-Benzyl­sulfanyl-2-[(2-chloro­phen­yl)diazen­yl]benzene
title_full 1-Benzyl­sulfanyl-2-[(2-chloro­phen­yl)diazen­yl]benzene
title_fullStr 1-Benzyl­sulfanyl-2-[(2-chloro­phen­yl)diazen­yl]benzene
title_full_unstemmed 1-Benzyl­sulfanyl-2-[(2-chloro­phen­yl)diazen­yl]benzene
title_short 1-Benzyl­sulfanyl-2-[(2-chloro­phen­yl)diazen­yl]benzene
title_sort 1-benzyl­sulfanyl-2-[(2-chloro­phen­yl)diazen­yl]benzene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007467/
https://www.ncbi.nlm.nih.gov/pubmed/21588269
http://dx.doi.org/10.1107/S1600536810025730
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AT bhattacharjeetirtha 1benzylsulfanyl22chlorophenyldiazenylbenzene
AT sarmarupam 1benzylsulfanyl22chlorophenyldiazenylbenzene

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