Methyl 4-(4-chloro­phen­yl)-3,3a,4,4a,5,12c-hexa­hydro-2-thia­naphtho­[1′,2′:3,2]furo[5,4-b]pyrrolizine-4a-carboxyl­ate

In the title compound, C(25)H(22)ClNO(3)S, both the pyrrolidinyl and thia­zolyl rings adopt envelope conformations whereas the dihydro­pyran ring adopts a half-chair conformation. The chloro­phenyl and naphthalenyl ring systems are oriented at a dihedral angle of 59.7 (1)°. The crystal packing is st...

Descripción completa

Detalles Bibliográficos
Autores principales: Selvanayagam, S., Sridhar, B., Ravikumar, K., Kathiravan, S., Raghunathan, R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007469/
https://www.ncbi.nlm.nih.gov/pubmed/21588391
http://dx.doi.org/10.1107/S1600536810028746
_version_ 1782194365164158976
author Selvanayagam, S.
Sridhar, B.
Ravikumar, K.
Kathiravan, S.
Raghunathan, R.
author_facet Selvanayagam, S.
Sridhar, B.
Ravikumar, K.
Kathiravan, S.
Raghunathan, R.
author_sort Selvanayagam, S.
collection PubMed
description In the title compound, C(25)H(22)ClNO(3)S, both the pyrrolidinyl and thia­zolyl rings adopt envelope conformations whereas the dihydro­pyran ring adopts a half-chair conformation. The chloro­phenyl and naphthalenyl ring systems are oriented at a dihedral angle of 59.7 (1)°. The crystal packing is stabilized by an intra­molecular C—H⋯N hydrogen bond and weak inter­molecular C—H⋯π inter­actions.
format Text
id pubmed-3007469
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30074692010-12-30 Methyl 4-(4-chloro­phen­yl)-3,3a,4,4a,5,12c-hexa­hydro-2-thia­naphtho­[1′,2′:3,2]furo[5,4-b]pyrrolizine-4a-carboxyl­ate Selvanayagam, S. Sridhar, B. Ravikumar, K. Kathiravan, S. Raghunathan, R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(22)ClNO(3)S, both the pyrrolidinyl and thia­zolyl rings adopt envelope conformations whereas the dihydro­pyran ring adopts a half-chair conformation. The chloro­phenyl and naphthalenyl ring systems are oriented at a dihedral angle of 59.7 (1)°. The crystal packing is stabilized by an intra­molecular C—H⋯N hydrogen bond and weak inter­molecular C—H⋯π inter­actions. International Union of Crystallography 2010-07-24 /pmc/articles/PMC3007469/ /pubmed/21588391 http://dx.doi.org/10.1107/S1600536810028746 Text en © Selvanayagam et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Selvanayagam, S.
Sridhar, B.
Ravikumar, K.
Kathiravan, S.
Raghunathan, R.
Methyl 4-(4-chloro­phen­yl)-3,3a,4,4a,5,12c-hexa­hydro-2-thia­naphtho­[1′,2′:3,2]furo[5,4-b]pyrrolizine-4a-carboxyl­ate
title Methyl 4-(4-chloro­phen­yl)-3,3a,4,4a,5,12c-hexa­hydro-2-thia­naphtho­[1′,2′:3,2]furo[5,4-b]pyrrolizine-4a-carboxyl­ate
title_full Methyl 4-(4-chloro­phen­yl)-3,3a,4,4a,5,12c-hexa­hydro-2-thia­naphtho­[1′,2′:3,2]furo[5,4-b]pyrrolizine-4a-carboxyl­ate
title_fullStr Methyl 4-(4-chloro­phen­yl)-3,3a,4,4a,5,12c-hexa­hydro-2-thia­naphtho­[1′,2′:3,2]furo[5,4-b]pyrrolizine-4a-carboxyl­ate
title_full_unstemmed Methyl 4-(4-chloro­phen­yl)-3,3a,4,4a,5,12c-hexa­hydro-2-thia­naphtho­[1′,2′:3,2]furo[5,4-b]pyrrolizine-4a-carboxyl­ate
title_short Methyl 4-(4-chloro­phen­yl)-3,3a,4,4a,5,12c-hexa­hydro-2-thia­naphtho­[1′,2′:3,2]furo[5,4-b]pyrrolizine-4a-carboxyl­ate
title_sort methyl 4-(4-chloro­phen­yl)-3,3a,4,4a,5,12c-hexa­hydro-2-thia­naphtho­[1′,2′:3,2]furo[5,4-b]pyrrolizine-4a-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007469/
https://www.ncbi.nlm.nih.gov/pubmed/21588391
http://dx.doi.org/10.1107/S1600536810028746
work_keys_str_mv AT selvanayagams methyl44chlorophenyl33a44a512chexahydro2thianaphtho1232furo54bpyrrolizine4acarboxylate
AT sridharb methyl44chlorophenyl33a44a512chexahydro2thianaphtho1232furo54bpyrrolizine4acarboxylate
AT ravikumark methyl44chlorophenyl33a44a512chexahydro2thianaphtho1232furo54bpyrrolizine4acarboxylate
AT kathiravans methyl44chlorophenyl33a44a512chexahydro2thianaphtho1232furo54bpyrrolizine4acarboxylate
AT raghunathanr methyl44chlorophenyl33a44a512chexahydro2thianaphtho1232furo54bpyrrolizine4acarboxylate

Ejemplares similares