1,5-Bis[2,6-bis­(2,4,6-triisopropyl­phen­yl)phen­yl]-2,3,4,6,7-penta­tellura-1,5-di­stannabicyclo­[3.1.1]hepta­ne

The title compound, [Sn(2)(C(72)H(98))Te(2)(Te(3))], has a cage-like structure with bulky aryl substituents on the Sn atoms. The mol­ecule sits over a crystallographic twofold axis, and hence the asymmetric unit consists of one half-mol­ecule. Due to the twofold axis, the tritelluride part has a 1:1...

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Detalles Bibliográficos
Autores principales: Saito, Masaichi, Hashimoto, Hizuru, Tajima, Tomoyuki
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007470/
https://www.ncbi.nlm.nih.gov/pubmed/21588131
http://dx.doi.org/10.1107/S1600536810025729
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author Saito, Masaichi
Hashimoto, Hizuru
Tajima, Tomoyuki
author_facet Saito, Masaichi
Hashimoto, Hizuru
Tajima, Tomoyuki
author_sort Saito, Masaichi
collection PubMed
description The title compound, [Sn(2)(C(72)H(98))Te(2)(Te(3))], has a cage-like structure with bulky aryl substituents on the Sn atoms. The mol­ecule sits over a crystallographic twofold axis, and hence the asymmetric unit consists of one half-mol­ecule. Due to the twofold axis, the tritelluride part has a 1:1 disorder. One of the six-membered rings has a boat conformation, whereas the other has a chair conformation. The ditelluradistannane ring has a bent structure, with a dihedral angle of 32.89 (2)° between the two Te—Sn—Te planes.
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spelling pubmed-30074702010-12-30 1,5-Bis[2,6-bis­(2,4,6-triisopropyl­phen­yl)phen­yl]-2,3,4,6,7-penta­tellura-1,5-di­stannabicyclo­[3.1.1]hepta­ne Saito, Masaichi Hashimoto, Hizuru Tajima, Tomoyuki Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Sn(2)(C(72)H(98))Te(2)(Te(3))], has a cage-like structure with bulky aryl substituents on the Sn atoms. The mol­ecule sits over a crystallographic twofold axis, and hence the asymmetric unit consists of one half-mol­ecule. Due to the twofold axis, the tritelluride part has a 1:1 disorder. One of the six-membered rings has a boat conformation, whereas the other has a chair conformation. The ditelluradistannane ring has a bent structure, with a dihedral angle of 32.89 (2)° between the two Te—Sn—Te planes. International Union of Crystallography 2010-07-03 /pmc/articles/PMC3007470/ /pubmed/21588131 http://dx.doi.org/10.1107/S1600536810025729 Text en © Saito et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Saito, Masaichi
Hashimoto, Hizuru
Tajima, Tomoyuki
1,5-Bis[2,6-bis­(2,4,6-triisopropyl­phen­yl)phen­yl]-2,3,4,6,7-penta­tellura-1,5-di­stannabicyclo­[3.1.1]hepta­ne
title 1,5-Bis[2,6-bis­(2,4,6-triisopropyl­phen­yl)phen­yl]-2,3,4,6,7-penta­tellura-1,5-di­stannabicyclo­[3.1.1]hepta­ne
title_full 1,5-Bis[2,6-bis­(2,4,6-triisopropyl­phen­yl)phen­yl]-2,3,4,6,7-penta­tellura-1,5-di­stannabicyclo­[3.1.1]hepta­ne
title_fullStr 1,5-Bis[2,6-bis­(2,4,6-triisopropyl­phen­yl)phen­yl]-2,3,4,6,7-penta­tellura-1,5-di­stannabicyclo­[3.1.1]hepta­ne
title_full_unstemmed 1,5-Bis[2,6-bis­(2,4,6-triisopropyl­phen­yl)phen­yl]-2,3,4,6,7-penta­tellura-1,5-di­stannabicyclo­[3.1.1]hepta­ne
title_short 1,5-Bis[2,6-bis­(2,4,6-triisopropyl­phen­yl)phen­yl]-2,3,4,6,7-penta­tellura-1,5-di­stannabicyclo­[3.1.1]hepta­ne
title_sort 1,5-bis[2,6-bis­(2,4,6-triisopropyl­phen­yl)phen­yl]-2,3,4,6,7-penta­tellura-1,5-di­stannabicyclo­[3.1.1]hepta­ne
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007470/
https://www.ncbi.nlm.nih.gov/pubmed/21588131
http://dx.doi.org/10.1107/S1600536810025729
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AT hashimotohizuru 15bis26bis246triisopropylphenylphenyl23467pentatellura15distannabicyclo311heptane
AT tajimatomoyuki 15bis26bis246triisopropylphenylphenyl23467pentatellura15distannabicyclo311heptane

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