Dichlorido[(S)-N-(1-phenyl­ethyl­idene)-1-(pyridin-2-yl)ethanamine-κ(2) N,N′]zinc(II) dichloro­methane solvate

In the title compound, [ZnCl(2)(C(15)H(16)N(2))]·CH(2)Cl(2), the Zn(II) atom has a distorted tetra­hedral coordination by two Cl atoms and two N atoms from the organic ligand [the average Zn—N and Zn—Cl bond lengths are 2.060 (4) Å and Zn—Cl = 2.179 (16) Å, respectively]. The dihedral angle between...

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Detalles Bibliográficos
Autores principales: Nayab, Saira, Paek, Seung-Min, Jeong, Jong Hwa
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007472/
https://www.ncbi.nlm.nih.gov/pubmed/21588102
http://dx.doi.org/10.1107/S1600536810029387
Descripción
Sumario:In the title compound, [ZnCl(2)(C(15)H(16)N(2))]·CH(2)Cl(2), the Zn(II) atom has a distorted tetra­hedral coordination by two Cl atoms and two N atoms from the organic ligand [the average Zn—N and Zn—Cl bond lengths are 2.060 (4) Å and Zn—Cl = 2.179 (16) Å, respectively]. The dihedral angle between the N—Zn—N and Cl—Zn—Cl planes is 89.9 (1)°. The phenyl ring forms a dihedral angle of 40.6 (5)° with the imine plane.

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