Dichlorido[(S)-N-(1-phenyl­ethyl­idene)-1-(pyridin-2-yl)ethanamine-κ(2) N,N′]zinc(II) dichloro­methane solvate

In the title compound, [ZnCl(2)(C(15)H(16)N(2))]·CH(2)Cl(2), the Zn(II) atom has a distorted tetra­hedral coordination by two Cl atoms and two N atoms from the organic ligand [the average Zn—N and Zn—Cl bond lengths are 2.060 (4) Å and Zn—Cl = 2.179 (16) Å, respectively]. The dihedral angle between...

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Detalles Bibliográficos
Autores principales: Nayab, Saira, Paek, Seung-Min, Jeong, Jong Hwa
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007472/
https://www.ncbi.nlm.nih.gov/pubmed/21588102
http://dx.doi.org/10.1107/S1600536810029387
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author Nayab, Saira
Paek, Seung-Min
Jeong, Jong Hwa
author_facet Nayab, Saira
Paek, Seung-Min
Jeong, Jong Hwa
author_sort Nayab, Saira
collection PubMed
description In the title compound, [ZnCl(2)(C(15)H(16)N(2))]·CH(2)Cl(2), the Zn(II) atom has a distorted tetra­hedral coordination by two Cl atoms and two N atoms from the organic ligand [the average Zn—N and Zn—Cl bond lengths are 2.060 (4) Å and Zn—Cl = 2.179 (16) Å, respectively]. The dihedral angle between the N—Zn—N and Cl—Zn—Cl planes is 89.9 (1)°. The phenyl ring forms a dihedral angle of 40.6 (5)° with the imine plane.
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spelling pubmed-30074722010-12-30 Dichlorido[(S)-N-(1-phenyl­ethyl­idene)-1-(pyridin-2-yl)ethanamine-κ(2) N,N′]zinc(II) dichloro­methane solvate Nayab, Saira Paek, Seung-Min Jeong, Jong Hwa Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ZnCl(2)(C(15)H(16)N(2))]·CH(2)Cl(2), the Zn(II) atom has a distorted tetra­hedral coordination by two Cl atoms and two N atoms from the organic ligand [the average Zn—N and Zn—Cl bond lengths are 2.060 (4) Å and Zn—Cl = 2.179 (16) Å, respectively]. The dihedral angle between the N—Zn—N and Cl—Zn—Cl planes is 89.9 (1)°. The phenyl ring forms a dihedral angle of 40.6 (5)° with the imine plane. International Union of Crystallography 2010-07-31 /pmc/articles/PMC3007472/ /pubmed/21588102 http://dx.doi.org/10.1107/S1600536810029387 Text en © Nayab et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nayab, Saira
Paek, Seung-Min
Jeong, Jong Hwa
Dichlorido[(S)-N-(1-phenyl­ethyl­idene)-1-(pyridin-2-yl)ethanamine-κ(2) N,N′]zinc(II) dichloro­methane solvate
title Dichlorido[(S)-N-(1-phenyl­ethyl­idene)-1-(pyridin-2-yl)ethanamine-κ(2) N,N′]zinc(II) dichloro­methane solvate
title_full Dichlorido[(S)-N-(1-phenyl­ethyl­idene)-1-(pyridin-2-yl)ethanamine-κ(2) N,N′]zinc(II) dichloro­methane solvate
title_fullStr Dichlorido[(S)-N-(1-phenyl­ethyl­idene)-1-(pyridin-2-yl)ethanamine-κ(2) N,N′]zinc(II) dichloro­methane solvate
title_full_unstemmed Dichlorido[(S)-N-(1-phenyl­ethyl­idene)-1-(pyridin-2-yl)ethanamine-κ(2) N,N′]zinc(II) dichloro­methane solvate
title_short Dichlorido[(S)-N-(1-phenyl­ethyl­idene)-1-(pyridin-2-yl)ethanamine-κ(2) N,N′]zinc(II) dichloro­methane solvate
title_sort dichlorido[(s)-n-(1-phenyl­ethyl­idene)-1-(pyridin-2-yl)ethanamine-κ(2) n,n′]zinc(ii) dichloro­methane solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007472/
https://www.ncbi.nlm.nih.gov/pubmed/21588102
http://dx.doi.org/10.1107/S1600536810029387
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AT paekseungmin dichloridosn1phenylethylidene1pyridin2ylethanaminek2nnzinciidichloromethanesolvate
AT jeongjonghwa dichloridosn1phenylethylidene1pyridin2ylethanaminek2nnzinciidichloromethanesolvate

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