Aqua(dimethylformamide){tris[(1-methyl-1H-benzimidazol-2-yl)methyl]amine}nickel(II) dipicrate

In the title complex, [Ni(C(27)H(27)N(7))(C(3)H(7)NO)(H(2)O)](C(6)H(2)N(3)O(7))(2), the Ni(II) ion is coordinated in a slightly distorted octa­hedral coordination evironment by an NiN(4)O(2) ligand set. The tris­(N-methyl­benzimidazol-2-ylmeth­yl)amine ligand is in a tetra­dentate mode while a coord...

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Detalles Bibliográficos
Autores principales: Li, Ke, Sun, Tao, Yang, Yang, Jia, Beibei, Wu, Huilu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007476/
https://www.ncbi.nlm.nih.gov/pubmed/21588100
http://dx.doi.org/10.1107/S1600536810029181
Descripción
Sumario:In the title complex, [Ni(C(27)H(27)N(7))(C(3)H(7)NO)(H(2)O)](C(6)H(2)N(3)O(7))(2), the Ni(II) ion is coordinated in a slightly distorted octa­hedral coordination evironment by an NiN(4)O(2) ligand set. The tris­(N-methyl­benzimidazol-2-ylmeth­yl)amine ligand is in a tetra­dentate mode while a coordinated water molecule and a dimethyl­formamide ligand complete the coordination. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the cation and one of the pictrate anions into four-component centrosymmetric clusters.

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