Diacetato­(N,N-diethyl­ethylenediamine)­zinc(II)

In the title compound, [Zn(CH(3)COO)(2)(C(6)H(16)N(2))], the Zn(II) atom is coordinated by two N atoms of one bidentate diethyl­ethylenediamine ligand and two O atoms of two acetate anions in a distorted tetra­hedral geometry. The acetate ligands are asymmetrically coordinated to the Zn atom with tw...

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Detalles Bibliográficos
Autores principales: Kim, Young-Inn, Yun, Sun-Young, Lee, Taewoo, Kang, Sung Kwon
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007483/
https://www.ncbi.nlm.nih.gov/pubmed/21588172
http://dx.doi.org/10.1107/S1600536810027418
Descripción
Sumario:In the title compound, [Zn(CH(3)COO)(2)(C(6)H(16)N(2))], the Zn(II) atom is coordinated by two N atoms of one bidentate diethyl­ethylenediamine ligand and two O atoms of two acetate anions in a distorted tetra­hedral geometry. The acetate ligands are asymmetrically coordinated to the Zn atom with two different C—O distances of 1.234 (4) and 1.275 (4) Å. The dihedral angle between the N/Zn/N and O/Zn/O planes is 83.11 (8)°. There are two independent mol­ecules in the asymmetric unit. N—H⋯O hydrogen bonding links mol­ecules into a three-dimensional network.

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