Diacetato­(N,N-diethyl­ethylenediamine)­zinc(II)

In the title compound, [Zn(CH(3)COO)(2)(C(6)H(16)N(2))], the Zn(II) atom is coordinated by two N atoms of one bidentate diethyl­ethylenediamine ligand and two O atoms of two acetate anions in a distorted tetra­hedral geometry. The acetate ligands are asymmetrically coordinated to the Zn atom with tw...

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Detalles Bibliográficos
Autores principales: Kim, Young-Inn, Yun, Sun-Young, Lee, Taewoo, Kang, Sung Kwon
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007483/
https://www.ncbi.nlm.nih.gov/pubmed/21588172
http://dx.doi.org/10.1107/S1600536810027418
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author Kim, Young-Inn
Yun, Sun-Young
Lee, Taewoo
Kang, Sung Kwon
author_facet Kim, Young-Inn
Yun, Sun-Young
Lee, Taewoo
Kang, Sung Kwon
author_sort Kim, Young-Inn
collection PubMed
description In the title compound, [Zn(CH(3)COO)(2)(C(6)H(16)N(2))], the Zn(II) atom is coordinated by two N atoms of one bidentate diethyl­ethylenediamine ligand and two O atoms of two acetate anions in a distorted tetra­hedral geometry. The acetate ligands are asymmetrically coordinated to the Zn atom with two different C—O distances of 1.234 (4) and 1.275 (4) Å. The dihedral angle between the N/Zn/N and O/Zn/O planes is 83.11 (8)°. There are two independent mol­ecules in the asymmetric unit. N—H⋯O hydrogen bonding links mol­ecules into a three-dimensional network.
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spelling pubmed-30074832010-12-30 Diacetato­(N,N-diethyl­ethylenediamine)­zinc(II) Kim, Young-Inn Yun, Sun-Young Lee, Taewoo Kang, Sung Kwon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(CH(3)COO)(2)(C(6)H(16)N(2))], the Zn(II) atom is coordinated by two N atoms of one bidentate diethyl­ethylenediamine ligand and two O atoms of two acetate anions in a distorted tetra­hedral geometry. The acetate ligands are asymmetrically coordinated to the Zn atom with two different C—O distances of 1.234 (4) and 1.275 (4) Å. The dihedral angle between the N/Zn/N and O/Zn/O planes is 83.11 (8)°. There are two independent mol­ecules in the asymmetric unit. N—H⋯O hydrogen bonding links mol­ecules into a three-dimensional network. International Union of Crystallography 2010-07-17 /pmc/articles/PMC3007483/ /pubmed/21588172 http://dx.doi.org/10.1107/S1600536810027418 Text en © Kim et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kim, Young-Inn
Yun, Sun-Young
Lee, Taewoo
Kang, Sung Kwon
Diacetato­(N,N-diethyl­ethylenediamine)­zinc(II)
title Diacetato­(N,N-diethyl­ethylenediamine)­zinc(II)
title_full Diacetato­(N,N-diethyl­ethylenediamine)­zinc(II)
title_fullStr Diacetato­(N,N-diethyl­ethylenediamine)­zinc(II)
title_full_unstemmed Diacetato­(N,N-diethyl­ethylenediamine)­zinc(II)
title_short Diacetato­(N,N-diethyl­ethylenediamine)­zinc(II)
title_sort diacetato­(n,n-diethyl­ethylenediamine)­zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007483/
https://www.ncbi.nlm.nih.gov/pubmed/21588172
http://dx.doi.org/10.1107/S1600536810027418
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AT leetaewoo diacetatonndiethylethylenediaminezincii
AT kangsungkwon diacetatonndiethylethylenediaminezincii

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