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Diacetonitrile(3-{2-[8-(2-bromoethoxy)-9,10-dioxoanthracen-1-yloxy]ethyl}-1-(2-pyridylmethyl)imidazolium)silver(I) bis(hexafluoridophosphate)
The title compound, [Ag(C(27)H(23)BrN(3)O(4))(CH(3)CN)(2)](PF(6))(2), is a mononuclear salt species in which the silver(I) atom is coordinated by one ligand and two acetonitrile molecules and exhibits a distorted T-shaped coordination. The asymmetric unit contains one independent cation and two ind...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007485/ https://www.ncbi.nlm.nih.gov/pubmed/21588104 http://dx.doi.org/10.1107/S1600536810029739 |
Sumario: | The title compound, [Ag(C(27)H(23)BrN(3)O(4))(CH(3)CN)(2)](PF(6))(2), is a mononuclear salt species in which the silver(I) atom is coordinated by one ligand and two acetonitrile molecules and exhibits a distorted T-shaped coordination. The asymmetric unit contains one independent cation and two independent hexafluoridophosphate anions, one of which is disordered over two positions in a 0.756 (11):0.244 (11) ratio. Weak π–π interactions between the anthraquinone ring systems [centroid–centroid distance = 3.676 (3) Å], intermolecular Ag–π interactions [Cg⋯Ag = 3.405 Å] and C—H⋯π interactions between pairs of adjacent molecules are observed. |
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