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Diacetonitrile­(3-{2-[8-(2-bromo­eth­oxy)-9,10-dioxoanthracen-1-yl­oxy]eth­yl}-1-(2-pyridyl­meth­yl)imidazolium)silver(I) bis­(hexa­fluorido­phosphate)

The title compound, [Ag(C(27)H(23)BrN(3)O(4))(CH(3)CN)(2)](PF(6))(2), is a mononuclear salt species in which the silver(I) atom is coordinated by one ligand and two acetonitrile mol­ecules and exhibits a distorted T-shaped coordination. The asymmetric unit contains one independent cation and two ind...

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Detalles Bibliográficos
Autores principales: Wen, Qing-Song, Zhou, Cheng-Lin, Qin, Da-Bin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007485/
https://www.ncbi.nlm.nih.gov/pubmed/21588104
http://dx.doi.org/10.1107/S1600536810029739
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author Wen, Qing-Song
Zhou, Cheng-Lin
Qin, Da-Bin
author_facet Wen, Qing-Song
Zhou, Cheng-Lin
Qin, Da-Bin
author_sort Wen, Qing-Song
collection PubMed
description The title compound, [Ag(C(27)H(23)BrN(3)O(4))(CH(3)CN)(2)](PF(6))(2), is a mononuclear salt species in which the silver(I) atom is coordinated by one ligand and two acetonitrile mol­ecules and exhibits a distorted T-shaped coordination. The asymmetric unit contains one independent cation and two independent hexa­fluorido­phosphate anions, one of which is disordered over two positions in a 0.756 (11):0.244 (11) ratio. Weak π–π inter­actions between the anthraquinone ring systems [centroid–centroid distance = 3.676 (3) Å], inter­molecular Ag–π inter­actions [Cg⋯Ag = 3.405 Å] and C—H⋯π inter­actions between pairs of adjacent mol­ecules are observed.
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spelling pubmed-30074852010-12-30 Diacetonitrile­(3-{2-[8-(2-bromo­eth­oxy)-9,10-dioxoanthracen-1-yl­oxy]eth­yl}-1-(2-pyridyl­meth­yl)imidazolium)silver(I) bis­(hexa­fluorido­phosphate) Wen, Qing-Song Zhou, Cheng-Lin Qin, Da-Bin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ag(C(27)H(23)BrN(3)O(4))(CH(3)CN)(2)](PF(6))(2), is a mononuclear salt species in which the silver(I) atom is coordinated by one ligand and two acetonitrile mol­ecules and exhibits a distorted T-shaped coordination. The asymmetric unit contains one independent cation and two independent hexa­fluorido­phosphate anions, one of which is disordered over two positions in a 0.756 (11):0.244 (11) ratio. Weak π–π inter­actions between the anthraquinone ring systems [centroid–centroid distance = 3.676 (3) Å], inter­molecular Ag–π inter­actions [Cg⋯Ag = 3.405 Å] and C—H⋯π inter­actions between pairs of adjacent mol­ecules are observed. International Union of Crystallography 2010-07-31 /pmc/articles/PMC3007485/ /pubmed/21588104 http://dx.doi.org/10.1107/S1600536810029739 Text en © Wen et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wen, Qing-Song
Zhou, Cheng-Lin
Qin, Da-Bin
Diacetonitrile­(3-{2-[8-(2-bromo­eth­oxy)-9,10-dioxoanthracen-1-yl­oxy]eth­yl}-1-(2-pyridyl­meth­yl)imidazolium)silver(I) bis­(hexa­fluorido­phosphate)
title Diacetonitrile­(3-{2-[8-(2-bromo­eth­oxy)-9,10-dioxoanthracen-1-yl­oxy]eth­yl}-1-(2-pyridyl­meth­yl)imidazolium)silver(I) bis­(hexa­fluorido­phosphate)
title_full Diacetonitrile­(3-{2-[8-(2-bromo­eth­oxy)-9,10-dioxoanthracen-1-yl­oxy]eth­yl}-1-(2-pyridyl­meth­yl)imidazolium)silver(I) bis­(hexa­fluorido­phosphate)
title_fullStr Diacetonitrile­(3-{2-[8-(2-bromo­eth­oxy)-9,10-dioxoanthracen-1-yl­oxy]eth­yl}-1-(2-pyridyl­meth­yl)imidazolium)silver(I) bis­(hexa­fluorido­phosphate)
title_full_unstemmed Diacetonitrile­(3-{2-[8-(2-bromo­eth­oxy)-9,10-dioxoanthracen-1-yl­oxy]eth­yl}-1-(2-pyridyl­meth­yl)imidazolium)silver(I) bis­(hexa­fluorido­phosphate)
title_short Diacetonitrile­(3-{2-[8-(2-bromo­eth­oxy)-9,10-dioxoanthracen-1-yl­oxy]eth­yl}-1-(2-pyridyl­meth­yl)imidazolium)silver(I) bis­(hexa­fluorido­phosphate)
title_sort diacetonitrile­(3-{2-[8-(2-bromo­eth­oxy)-9,10-dioxoanthracen-1-yl­oxy]eth­yl}-1-(2-pyridyl­meth­yl)imidazolium)silver(i) bis­(hexa­fluorido­phosphate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007485/
https://www.ncbi.nlm.nih.gov/pubmed/21588104
http://dx.doi.org/10.1107/S1600536810029739
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