catena-Poly[[tris­(4-fluoro­benz­yl)tin(IV)]-μ-2-[(piperidin-1-yl)carbothio­ylsulfan­yl]acetato-κ(2) O:O′]

Adjacent units of the title polymeric complex, [Sn(C(7)H(6)F)(3)(C(8)H(12)NO(2)S(2))], are bridged by the carboxyl­ate ion into a helical chain running along the b axis. The Sn(IV) atom shows a distorted trans-C(3)SnO(2) trigonal-bipyramidal coordination and is displaced by 0.113 (2) Å out of the C(...

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Detalles Bibliográficos
Autores principales: Keng, Chun Thy, Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007486/
https://www.ncbi.nlm.nih.gov/pubmed/21588202
http://dx.doi.org/10.1107/S1600536810028321
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author Keng, Chun Thy
Lo, Kong Mun
Ng, Seik Weng
author_facet Keng, Chun Thy
Lo, Kong Mun
Ng, Seik Weng
author_sort Keng, Chun Thy
collection PubMed
description Adjacent units of the title polymeric complex, [Sn(C(7)H(6)F)(3)(C(8)H(12)NO(2)S(2))], are bridged by the carboxyl­ate ion into a helical chain running along the b axis. The Sn(IV) atom shows a distorted trans-C(3)SnO(2) trigonal-bipyramidal coordination and is displaced by 0.113 (2) Å out of the C(3)Sn girdle in the direction of the covalently bonded O atom. The ring is disordered of two positions with an occupancy of 0.631 (4) for the major occupied site.
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spelling pubmed-30074862010-12-30 catena-Poly[[tris­(4-fluoro­benz­yl)tin(IV)]-μ-2-[(piperidin-1-yl)carbothio­ylsulfan­yl]acetato-κ(2) O:O′] Keng, Chun Thy Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Adjacent units of the title polymeric complex, [Sn(C(7)H(6)F)(3)(C(8)H(12)NO(2)S(2))], are bridged by the carboxyl­ate ion into a helical chain running along the b axis. The Sn(IV) atom shows a distorted trans-C(3)SnO(2) trigonal-bipyramidal coordination and is displaced by 0.113 (2) Å out of the C(3)Sn girdle in the direction of the covalently bonded O atom. The ring is disordered of two positions with an occupancy of 0.631 (4) for the major occupied site. International Union of Crystallography 2010-07-21 /pmc/articles/PMC3007486/ /pubmed/21588202 http://dx.doi.org/10.1107/S1600536810028321 Text en © Keng et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Keng, Chun Thy
Lo, Kong Mun
Ng, Seik Weng
catena-Poly[[tris­(4-fluoro­benz­yl)tin(IV)]-μ-2-[(piperidin-1-yl)carbothio­ylsulfan­yl]acetato-κ(2) O:O′]
title catena-Poly[[tris­(4-fluoro­benz­yl)tin(IV)]-μ-2-[(piperidin-1-yl)carbothio­ylsulfan­yl]acetato-κ(2) O:O′]
title_full catena-Poly[[tris­(4-fluoro­benz­yl)tin(IV)]-μ-2-[(piperidin-1-yl)carbothio­ylsulfan­yl]acetato-κ(2) O:O′]
title_fullStr catena-Poly[[tris­(4-fluoro­benz­yl)tin(IV)]-μ-2-[(piperidin-1-yl)carbothio­ylsulfan­yl]acetato-κ(2) O:O′]
title_full_unstemmed catena-Poly[[tris­(4-fluoro­benz­yl)tin(IV)]-μ-2-[(piperidin-1-yl)carbothio­ylsulfan­yl]acetato-κ(2) O:O′]
title_short catena-Poly[[tris­(4-fluoro­benz­yl)tin(IV)]-μ-2-[(piperidin-1-yl)carbothio­ylsulfan­yl]acetato-κ(2) O:O′]
title_sort catena-poly[[tris­(4-fluoro­benz­yl)tin(iv)]-μ-2-[(piperidin-1-yl)carbothio­ylsulfan­yl]acetato-κ(2) o:o′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007486/
https://www.ncbi.nlm.nih.gov/pubmed/21588202
http://dx.doi.org/10.1107/S1600536810028321
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AT ngseikweng catenapolytris4fluorobenzyltinivm2piperidin1ylcarbothioylsulfanylacetatok2oo

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