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Diaqua­bis­(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))nickel(II) tetra­hydrate

In the title complex, [Ni(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·4H(2)O, the Ni(II) ion is coordinated in a slightly distorted octa­hedral environment formed by two bis-chelating H(2)pimda (H(3)pimda is 2-propyl-1H-4,5-dicarb­oxy­lic acid) ligands and two coordinated water mol­ecules. In the crystal struct...

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Detalles Bibliográficos
Autores principales: Fan, Run-Zhen, Li, Shi-Jie, Song, Wen-Dong, Miao, Dong-Liang, Hu, Shi-Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007488/
https://www.ncbi.nlm.nih.gov/pubmed/21588141
http://dx.doi.org/10.1107/S1600536810025237
Descripción
Sumario:In the title complex, [Ni(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·4H(2)O, the Ni(II) ion is coordinated in a slightly distorted octa­hedral environment formed by two bis-chelating H(2)pimda (H(3)pimda is 2-propyl-1H-4,5-dicarb­oxy­lic acid) ligands and two coordinated water mol­ecules. In the crystal structure, a three-dimensional framework is formed by inter­molecular O—H⋯O and N—H⋯O hydrogen bonds involving the solvent water mol­ecules, coordinated water mol­ecules, carboxyl­ate O atoms and the protonated N atoms of the H(2)pimda ligands. The propyl groups of each H(2)pimda ligand are disordered over two sets of sites with refined occupancies of 0.50 (2):0.50 (2) and 0.762 (11):0.238 (11). In one water solvent mol­ecule, one of the H atoms was refined as disordered over two sites of equal occupancy.