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Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2) N (3),O (4))nickel(II) tetrahydrate
In the title complex, [Ni(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·4H(2)O, the Ni(II) ion is coordinated in a slightly distorted octahedral environment formed by two bis-chelating H(2)pimda (H(3)pimda is 2-propyl-1H-4,5-dicarboxylic acid) ligands and two coordinated water molecules. In the crystal struct...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007488/ https://www.ncbi.nlm.nih.gov/pubmed/21588141 http://dx.doi.org/10.1107/S1600536810025237 |
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author | Fan, Run-Zhen Li, Shi-Jie Song, Wen-Dong Miao, Dong-Liang Hu, Shi-Wei |
author_facet | Fan, Run-Zhen Li, Shi-Jie Song, Wen-Dong Miao, Dong-Liang Hu, Shi-Wei |
author_sort | Fan, Run-Zhen |
collection | PubMed |
description | In the title complex, [Ni(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·4H(2)O, the Ni(II) ion is coordinated in a slightly distorted octahedral environment formed by two bis-chelating H(2)pimda (H(3)pimda is 2-propyl-1H-4,5-dicarboxylic acid) ligands and two coordinated water molecules. In the crystal structure, a three-dimensional framework is formed by intermolecular O—H⋯O and N—H⋯O hydrogen bonds involving the solvent water molecules, coordinated water molecules, carboxylate O atoms and the protonated N atoms of the H(2)pimda ligands. The propyl groups of each H(2)pimda ligand are disordered over two sets of sites with refined occupancies of 0.50 (2):0.50 (2) and 0.762 (11):0.238 (11). In one water solvent molecule, one of the H atoms was refined as disordered over two sites of equal occupancy. |
format | Text |
id | pubmed-3007488 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30074882010-12-30 Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2) N (3),O (4))nickel(II) tetrahydrate Fan, Run-Zhen Li, Shi-Jie Song, Wen-Dong Miao, Dong-Liang Hu, Shi-Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·4H(2)O, the Ni(II) ion is coordinated in a slightly distorted octahedral environment formed by two bis-chelating H(2)pimda (H(3)pimda is 2-propyl-1H-4,5-dicarboxylic acid) ligands and two coordinated water molecules. In the crystal structure, a three-dimensional framework is formed by intermolecular O—H⋯O and N—H⋯O hydrogen bonds involving the solvent water molecules, coordinated water molecules, carboxylate O atoms and the protonated N atoms of the H(2)pimda ligands. The propyl groups of each H(2)pimda ligand are disordered over two sets of sites with refined occupancies of 0.50 (2):0.50 (2) and 0.762 (11):0.238 (11). In one water solvent molecule, one of the H atoms was refined as disordered over two sites of equal occupancy. International Union of Crystallography 2010-07-07 /pmc/articles/PMC3007488/ /pubmed/21588141 http://dx.doi.org/10.1107/S1600536810025237 Text en © Fan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Fan, Run-Zhen Li, Shi-Jie Song, Wen-Dong Miao, Dong-Liang Hu, Shi-Wei Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2) N (3),O (4))nickel(II) tetrahydrate |
title | Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))nickel(II) tetrahydrate |
title_full | Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))nickel(II) tetrahydrate |
title_fullStr | Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))nickel(II) tetrahydrate |
title_full_unstemmed | Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))nickel(II) tetrahydrate |
title_short | Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))nickel(II) tetrahydrate |
title_sort | diaquabis(5-carboxy-2-propyl-1h-imidazole-4-carboxylato-κ(2)
n
(3),o
(4))nickel(ii) tetrahydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007488/ https://www.ncbi.nlm.nih.gov/pubmed/21588141 http://dx.doi.org/10.1107/S1600536810025237 |
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