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Diaqua­bis­(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))nickel(II) tetra­hydrate

In the title complex, [Ni(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·4H(2)O, the Ni(II) ion is coordinated in a slightly distorted octa­hedral environment formed by two bis-chelating H(2)pimda (H(3)pimda is 2-propyl-1H-4,5-dicarb­oxy­lic acid) ligands and two coordinated water mol­ecules. In the crystal struct...

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Autores principales: Fan, Run-Zhen, Li, Shi-Jie, Song, Wen-Dong, Miao, Dong-Liang, Hu, Shi-Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007488/
https://www.ncbi.nlm.nih.gov/pubmed/21588141
http://dx.doi.org/10.1107/S1600536810025237
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author Fan, Run-Zhen
Li, Shi-Jie
Song, Wen-Dong
Miao, Dong-Liang
Hu, Shi-Wei
author_facet Fan, Run-Zhen
Li, Shi-Jie
Song, Wen-Dong
Miao, Dong-Liang
Hu, Shi-Wei
author_sort Fan, Run-Zhen
collection PubMed
description In the title complex, [Ni(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·4H(2)O, the Ni(II) ion is coordinated in a slightly distorted octa­hedral environment formed by two bis-chelating H(2)pimda (H(3)pimda is 2-propyl-1H-4,5-dicarb­oxy­lic acid) ligands and two coordinated water mol­ecules. In the crystal structure, a three-dimensional framework is formed by inter­molecular O—H⋯O and N—H⋯O hydrogen bonds involving the solvent water mol­ecules, coordinated water mol­ecules, carboxyl­ate O atoms and the protonated N atoms of the H(2)pimda ligands. The propyl groups of each H(2)pimda ligand are disordered over two sets of sites with refined occupancies of 0.50 (2):0.50 (2) and 0.762 (11):0.238 (11). In one water solvent mol­ecule, one of the H atoms was refined as disordered over two sites of equal occupancy.
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spelling pubmed-30074882010-12-30 Diaqua­bis­(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))nickel(II) tetra­hydrate Fan, Run-Zhen Li, Shi-Jie Song, Wen-Dong Miao, Dong-Liang Hu, Shi-Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·4H(2)O, the Ni(II) ion is coordinated in a slightly distorted octa­hedral environment formed by two bis-chelating H(2)pimda (H(3)pimda is 2-propyl-1H-4,5-dicarb­oxy­lic acid) ligands and two coordinated water mol­ecules. In the crystal structure, a three-dimensional framework is formed by inter­molecular O—H⋯O and N—H⋯O hydrogen bonds involving the solvent water mol­ecules, coordinated water mol­ecules, carboxyl­ate O atoms and the protonated N atoms of the H(2)pimda ligands. The propyl groups of each H(2)pimda ligand are disordered over two sets of sites with refined occupancies of 0.50 (2):0.50 (2) and 0.762 (11):0.238 (11). In one water solvent mol­ecule, one of the H atoms was refined as disordered over two sites of equal occupancy. International Union of Crystallography 2010-07-07 /pmc/articles/PMC3007488/ /pubmed/21588141 http://dx.doi.org/10.1107/S1600536810025237 Text en © Fan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fan, Run-Zhen
Li, Shi-Jie
Song, Wen-Dong
Miao, Dong-Liang
Hu, Shi-Wei
Diaqua­bis­(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))nickel(II) tetra­hydrate
title Diaqua­bis­(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))nickel(II) tetra­hydrate
title_full Diaqua­bis­(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))nickel(II) tetra­hydrate
title_fullStr Diaqua­bis­(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))nickel(II) tetra­hydrate
title_full_unstemmed Diaqua­bis­(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))nickel(II) tetra­hydrate
title_short Diaqua­bis­(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))nickel(II) tetra­hydrate
title_sort diaqua­bis­(5-carb­oxy-2-propyl-1h-imidazole-4-carboxyl­ato-κ(2) n (3),o (4))nickel(ii) tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007488/
https://www.ncbi.nlm.nih.gov/pubmed/21588141
http://dx.doi.org/10.1107/S1600536810025237
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