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Bis(2,6-diamino­pyridin-1-ium) hexa­aqua­cobalt(II) disulfate dihydrate

In the title compound, (C(5)H(8)N(3))(2)[Co(H(2)O)(6)](SO(4))(2)·2H(2)O, the complete complex cation is generated by crystallographic inversion symmetry, such that the Co(II) cation is octa­hedrally coordinated by six water mol­ecules. The organic cation is essentially planar, with a maximum deviati...

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Autores principales: Al-Dajani, Mohammad T. M., Wahab, Habibah A, Mohamed, Nornisah, Goh, Jia Hao, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007492/
https://www.ncbi.nlm.nih.gov/pubmed/21588154
http://dx.doi.org/10.1107/S1600536810026693
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author Al-Dajani, Mohammad T. M.
Wahab, Habibah A
Mohamed, Nornisah
Goh, Jia Hao
Fun, Hoong-Kun
author_facet Al-Dajani, Mohammad T. M.
Wahab, Habibah A
Mohamed, Nornisah
Goh, Jia Hao
Fun, Hoong-Kun
author_sort Al-Dajani, Mohammad T. M.
collection PubMed
description In the title compound, (C(5)H(8)N(3))(2)[Co(H(2)O)(6)](SO(4))(2)·2H(2)O, the complete complex cation is generated by crystallographic inversion symmetry, such that the Co(II) cation is octa­hedrally coordinated by six water mol­ecules. The organic cation is essentially planar, with a maximum deviation of 0.013 (1) Å. In the crystal structure, the ions and mol­ecules are linked into a pseudo-layered three-dimensional supra­molecular network via O—H⋯O and N—H⋯O hydrogen bonds. Weak inter­molecular π–π inter­actions further stabilize the crystal structure [centroid–centroid distance = 3.5231 (4) Å].
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spelling pubmed-30074922010-12-30 Bis(2,6-diamino­pyridin-1-ium) hexa­aqua­cobalt(II) disulfate dihydrate Al-Dajani, Mohammad T. M. Wahab, Habibah A Mohamed, Nornisah Goh, Jia Hao Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(5)H(8)N(3))(2)[Co(H(2)O)(6)](SO(4))(2)·2H(2)O, the complete complex cation is generated by crystallographic inversion symmetry, such that the Co(II) cation is octa­hedrally coordinated by six water mol­ecules. The organic cation is essentially planar, with a maximum deviation of 0.013 (1) Å. In the crystal structure, the ions and mol­ecules are linked into a pseudo-layered three-dimensional supra­molecular network via O—H⋯O and N—H⋯O hydrogen bonds. Weak inter­molecular π–π inter­actions further stabilize the crystal structure [centroid–centroid distance = 3.5231 (4) Å]. International Union of Crystallography 2010-07-10 /pmc/articles/PMC3007492/ /pubmed/21588154 http://dx.doi.org/10.1107/S1600536810026693 Text en © Al-Dajani et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Al-Dajani, Mohammad T. M.
Wahab, Habibah A
Mohamed, Nornisah
Goh, Jia Hao
Fun, Hoong-Kun
Bis(2,6-diamino­pyridin-1-ium) hexa­aqua­cobalt(II) disulfate dihydrate
title Bis(2,6-diamino­pyridin-1-ium) hexa­aqua­cobalt(II) disulfate dihydrate
title_full Bis(2,6-diamino­pyridin-1-ium) hexa­aqua­cobalt(II) disulfate dihydrate
title_fullStr Bis(2,6-diamino­pyridin-1-ium) hexa­aqua­cobalt(II) disulfate dihydrate
title_full_unstemmed Bis(2,6-diamino­pyridin-1-ium) hexa­aqua­cobalt(II) disulfate dihydrate
title_short Bis(2,6-diamino­pyridin-1-ium) hexa­aqua­cobalt(II) disulfate dihydrate
title_sort bis(2,6-diamino­pyridin-1-ium) hexa­aqua­cobalt(ii) disulfate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007492/
https://www.ncbi.nlm.nih.gov/pubmed/21588154
http://dx.doi.org/10.1107/S1600536810026693
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