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Bis(2,6-diaminopyridin-1-ium) hexaaquacobalt(II) disulfate dihydrate
In the title compound, (C(5)H(8)N(3))(2)[Co(H(2)O)(6)](SO(4))(2)·2H(2)O, the complete complex cation is generated by crystallographic inversion symmetry, such that the Co(II) cation is octahedrally coordinated by six water molecules. The organic cation is essentially planar, with a maximum deviati...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007492/ https://www.ncbi.nlm.nih.gov/pubmed/21588154 http://dx.doi.org/10.1107/S1600536810026693 |
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author | Al-Dajani, Mohammad T. M. Wahab, Habibah A Mohamed, Nornisah Goh, Jia Hao Fun, Hoong-Kun |
author_facet | Al-Dajani, Mohammad T. M. Wahab, Habibah A Mohamed, Nornisah Goh, Jia Hao Fun, Hoong-Kun |
author_sort | Al-Dajani, Mohammad T. M. |
collection | PubMed |
description | In the title compound, (C(5)H(8)N(3))(2)[Co(H(2)O)(6)](SO(4))(2)·2H(2)O, the complete complex cation is generated by crystallographic inversion symmetry, such that the Co(II) cation is octahedrally coordinated by six water molecules. The organic cation is essentially planar, with a maximum deviation of 0.013 (1) Å. In the crystal structure, the ions and molecules are linked into a pseudo-layered three-dimensional supramolecular network via O—H⋯O and N—H⋯O hydrogen bonds. Weak intermolecular π–π interactions further stabilize the crystal structure [centroid–centroid distance = 3.5231 (4) Å]. |
format | Text |
id | pubmed-3007492 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30074922010-12-30 Bis(2,6-diaminopyridin-1-ium) hexaaquacobalt(II) disulfate dihydrate Al-Dajani, Mohammad T. M. Wahab, Habibah A Mohamed, Nornisah Goh, Jia Hao Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(5)H(8)N(3))(2)[Co(H(2)O)(6)](SO(4))(2)·2H(2)O, the complete complex cation is generated by crystallographic inversion symmetry, such that the Co(II) cation is octahedrally coordinated by six water molecules. The organic cation is essentially planar, with a maximum deviation of 0.013 (1) Å. In the crystal structure, the ions and molecules are linked into a pseudo-layered three-dimensional supramolecular network via O—H⋯O and N—H⋯O hydrogen bonds. Weak intermolecular π–π interactions further stabilize the crystal structure [centroid–centroid distance = 3.5231 (4) Å]. International Union of Crystallography 2010-07-10 /pmc/articles/PMC3007492/ /pubmed/21588154 http://dx.doi.org/10.1107/S1600536810026693 Text en © Al-Dajani et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Al-Dajani, Mohammad T. M. Wahab, Habibah A Mohamed, Nornisah Goh, Jia Hao Fun, Hoong-Kun Bis(2,6-diaminopyridin-1-ium) hexaaquacobalt(II) disulfate dihydrate |
title | Bis(2,6-diaminopyridin-1-ium) hexaaquacobalt(II) disulfate dihydrate |
title_full | Bis(2,6-diaminopyridin-1-ium) hexaaquacobalt(II) disulfate dihydrate |
title_fullStr | Bis(2,6-diaminopyridin-1-ium) hexaaquacobalt(II) disulfate dihydrate |
title_full_unstemmed | Bis(2,6-diaminopyridin-1-ium) hexaaquacobalt(II) disulfate dihydrate |
title_short | Bis(2,6-diaminopyridin-1-ium) hexaaquacobalt(II) disulfate dihydrate |
title_sort | bis(2,6-diaminopyridin-1-ium) hexaaquacobalt(ii) disulfate dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007492/ https://www.ncbi.nlm.nih.gov/pubmed/21588154 http://dx.doi.org/10.1107/S1600536810026693 |
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