catena-Poly[[(1,10-phenanthroline)lead(II)]bis­(μ-5-chloro-2-hy­droxy­benzoato)]

In the title polymer, [Pb(C(7)H(4)ClO(3))(2)(C(12)H(8)N(2))](n), the Pb(II) ion displays a distorted pseudo-octa­hedral coordination geometry. The metal center is coordinated by six O atoms from four 5-chloro­salicylate ligands and two N atoms from a chelating phenanthroline ligand. The polymeric st...

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Detalles Bibliográficos
Autores principales: Yang, Lei, Li, Bing, Xue, Qing, Huo, Yu, Wang, Gaopeng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007493/
https://www.ncbi.nlm.nih.gov/pubmed/21588208
http://dx.doi.org/10.1107/S1600536810023561
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author Yang, Lei
Li, Bing
Xue, Qing
Huo, Yu
Wang, Gaopeng
author_facet Yang, Lei
Li, Bing
Xue, Qing
Huo, Yu
Wang, Gaopeng
author_sort Yang, Lei
collection PubMed
description In the title polymer, [Pb(C(7)H(4)ClO(3))(2)(C(12)H(8)N(2))](n), the Pb(II) ion displays a distorted pseudo-octa­hedral coordination geometry. The metal center is coordinated by six O atoms from four 5-chloro­salicylate ligands and two N atoms from a chelating phenanthroline ligand. The polymeric structure is built up from bridging carboxyl­ate O atoms, forming chains along [100]. The crystal structure is stabilized by π–π inter­actions between the 1,10-phenanthroline and 5-chloro­salicylate ligands, the shortest centroid–centroid separation between neighbouring aromatic rings being 3.652 (1) Å.
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spelling pubmed-30074932010-12-30 catena-Poly[[(1,10-phenanthroline)lead(II)]bis­(μ-5-chloro-2-hy­droxy­benzoato)] Yang, Lei Li, Bing Xue, Qing Huo, Yu Wang, Gaopeng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymer, [Pb(C(7)H(4)ClO(3))(2)(C(12)H(8)N(2))](n), the Pb(II) ion displays a distorted pseudo-octa­hedral coordination geometry. The metal center is coordinated by six O atoms from four 5-chloro­salicylate ligands and two N atoms from a chelating phenanthroline ligand. The polymeric structure is built up from bridging carboxyl­ate O atoms, forming chains along [100]. The crystal structure is stabilized by π–π inter­actions between the 1,10-phenanthroline and 5-chloro­salicylate ligands, the shortest centroid–centroid separation between neighbouring aromatic rings being 3.652 (1) Å. International Union of Crystallography 2010-07-21 /pmc/articles/PMC3007493/ /pubmed/21588208 http://dx.doi.org/10.1107/S1600536810023561 Text en © Yang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Lei
Li, Bing
Xue, Qing
Huo, Yu
Wang, Gaopeng
catena-Poly[[(1,10-phenanthroline)lead(II)]bis­(μ-5-chloro-2-hy­droxy­benzoato)]
title catena-Poly[[(1,10-phenanthroline)lead(II)]bis­(μ-5-chloro-2-hy­droxy­benzoato)]
title_full catena-Poly[[(1,10-phenanthroline)lead(II)]bis­(μ-5-chloro-2-hy­droxy­benzoato)]
title_fullStr catena-Poly[[(1,10-phenanthroline)lead(II)]bis­(μ-5-chloro-2-hy­droxy­benzoato)]
title_full_unstemmed catena-Poly[[(1,10-phenanthroline)lead(II)]bis­(μ-5-chloro-2-hy­droxy­benzoato)]
title_short catena-Poly[[(1,10-phenanthroline)lead(II)]bis­(μ-5-chloro-2-hy­droxy­benzoato)]
title_sort catena-poly[[(1,10-phenanthroline)lead(ii)]bis­(μ-5-chloro-2-hy­droxy­benzoato)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007493/
https://www.ncbi.nlm.nih.gov/pubmed/21588208
http://dx.doi.org/10.1107/S1600536810023561
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