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Bis[4-(2-benzoyl-1-oxidoethenyl)-3-hydroxyphenyl benzoato]diethanolcobalt(II)
In the title complex, [Co(C(22)H(15)O(5))(2)(C(2)H(5)OH)(2)], the Co(II) atom (site symmetry [Image: see text]) is coordinated by two O,O′-bidentate 4-(2-benzoyl-1-oxidoethenyl)-3-hydroxyphenyl benzoate anions and two ethanol O atoms, resulting in a slightly distorted CoO(6) octahedral coordinat...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007494/ https://www.ncbi.nlm.nih.gov/pubmed/21588110 http://dx.doi.org/10.1107/S1600536810029776 |
Sumario: | In the title complex, [Co(C(22)H(15)O(5))(2)(C(2)H(5)OH)(2)], the Co(II) atom (site symmetry [Image: see text]) is coordinated by two O,O′-bidentate 4-(2-benzoyl-1-oxidoethenyl)-3-hydroxyphenyl benzoate anions and two ethanol O atoms, resulting in a slightly distorted CoO(6) octahedral coordination. An intramolecular O—H⋯O hydrogen bond in the ligand generates an S(6) ring. The dihedral angle between the aromatic rings joined to the acetylacetonate unit is 6.4 (2)°. The ethanol molecule is disordered over two orientations in a 0.65 (3):0.35 (3) ratio. In the crystal, molecules are linked by O—H⋯O bonds. |
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