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Bis[4-(2-benzoyl-1-oxidoethen­yl)-3-hy­droxy­phenyl benzoato]diethano­l­cobalt(II)

In the title complex, [Co(C(22)H(15)O(5))(2)(C(2)H(5)OH)(2)], the Co(II) atom (site symmetry [Image: see text]) is coordinated by two O,O′-bidentate 4-(2-benzoyl-1-oxidoethen­yl)-3-hy­droxy­phenyl benzoate anions and two ethanol O atoms, resulting in a slightly distorted CoO(6) octa­hedral coordinat...

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Detalles Bibliográficos
Autores principales: Bai, Xue-Lian, Yue, Tian-Li, Yuan, Ya-Hong, Zhang, Hua-Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007494/
https://www.ncbi.nlm.nih.gov/pubmed/21588110
http://dx.doi.org/10.1107/S1600536810029776
Descripción
Sumario:In the title complex, [Co(C(22)H(15)O(5))(2)(C(2)H(5)OH)(2)], the Co(II) atom (site symmetry [Image: see text]) is coordinated by two O,O′-bidentate 4-(2-benzoyl-1-oxidoethen­yl)-3-hy­droxy­phenyl benzoate anions and two ethanol O atoms, resulting in a slightly distorted CoO(6) octa­hedral coordination. An intra­molecular O—H⋯O hydrogen bond in the ligand generates an S(6) ring. The dihedral angle between the aromatic rings joined to the acetyl­acetonate unit is 6.4 (2)°. The ethanol mol­ecule is disordered over two orientations in a 0.65 (3):0.35 (3) ratio. In the crystal, mol­ecules are linked by O—H⋯O bonds.