Tl(2)Mo(9)Se(11)

The structure of Tl(2)Mo(9)Se(11), dithallium nona­molybdenum undeca­selenide, is isotypic with Tl(2)Mo(9)S(11) [Potel et al. (1980 ▶). Acta Cryst. B36, 1319–1322]. The structural set-up is characterized by a mixture of Mo(6)Se(i) (8)Se(a) (6) and Mo(12)Se(i) (14)Se(a) (6) cluster units in a 1:1 rat...

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Detalles Bibliográficos
Autores principales: Gougeon, Patrick, Gall, Philippe, Potel, Michel
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007497/
https://www.ncbi.nlm.nih.gov/pubmed/21588079
http://dx.doi.org/10.1107/S1600536810026541
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author Gougeon, Patrick
Gall, Philippe
Potel, Michel
author_facet Gougeon, Patrick
Gall, Philippe
Potel, Michel
author_sort Gougeon, Patrick
collection PubMed
description The structure of Tl(2)Mo(9)Se(11), dithallium nona­molybdenum undeca­selenide, is isotypic with Tl(2)Mo(9)S(11) [Potel et al. (1980 ▶). Acta Cryst. B36, 1319–1322]. The structural set-up is characterized by a mixture of Mo(6)Se(i) (8)Se(a) (6) and Mo(12)Se(i) (14)Se(a) (6) cluster units in a 1:1 ratio. Both components are inter­connected through inter­unit Mo—Se bonds. The cluster units are centered at Wyckoff positions 3a and 3b (point-group symmetry [Image: see text].). The two Tl(I) atoms are situated in the voids of the three-dimensional arrangement. Two of the five independent Se atoms and the Tl atoms lie on sites with 3. symmetry (Wyckoff site 6c).
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spelling pubmed-30074972010-12-30 Tl(2)Mo(9)Se(11) Gougeon, Patrick Gall, Philippe Potel, Michel Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The structure of Tl(2)Mo(9)Se(11), dithallium nona­molybdenum undeca­selenide, is isotypic with Tl(2)Mo(9)S(11) [Potel et al. (1980 ▶). Acta Cryst. B36, 1319–1322]. The structural set-up is characterized by a mixture of Mo(6)Se(i) (8)Se(a) (6) and Mo(12)Se(i) (14)Se(a) (6) cluster units in a 1:1 ratio. Both components are inter­connected through inter­unit Mo—Se bonds. The cluster units are centered at Wyckoff positions 3a and 3b (point-group symmetry [Image: see text].). The two Tl(I) atoms are situated in the voids of the three-dimensional arrangement. Two of the five independent Se atoms and the Tl atoms lie on sites with 3. symmetry (Wyckoff site 6c). International Union of Crystallography 2010-07-10 /pmc/articles/PMC3007497/ /pubmed/21588079 http://dx.doi.org/10.1107/S1600536810026541 Text en © Gougeon et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Gougeon, Patrick
Gall, Philippe
Potel, Michel
Tl(2)Mo(9)Se(11)
title Tl(2)Mo(9)Se(11)
title_full Tl(2)Mo(9)Se(11)
title_fullStr Tl(2)Mo(9)Se(11)
title_full_unstemmed Tl(2)Mo(9)Se(11)
title_short Tl(2)Mo(9)Se(11)
title_sort tl(2)mo(9)se(11)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007497/
https://www.ncbi.nlm.nih.gov/pubmed/21588079
http://dx.doi.org/10.1107/S1600536810026541
work_keys_str_mv AT gougeonpatrick tl2mo9se11
AT gallphilippe tl2mo9se11
AT potelmichel tl2mo9se11

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