Cargando…

Poly[[bis­{μ(3)-2-[(3,5-dimethyl-1H-pyrazol-1-yl)(phen­yl)meth­yl]propane­dioato}tetra­sodium(I)] 7.5-hydrate]

The asymmetric unit of the title polymer, {[Na(4)(C(15)H(14)N(2)O(4))(2)]·7.5H(2)O}(n), contains two 2-[(3,5-dimethyl-1H-pyrazol-1-yl)(phen­yl)meth­yl]propane­dioate (ppmp) anions, eight water mol­ecules (one located on a twofold rotation axis) and five sodium cations (one located on an inversion ce...

Descripción completa

Detalles Bibliográficos
Autores principales: Meskini, Ihssan, Daoudi, Maria, Daran, Jean-Claude, Ben Hadda, Taibi, Zouihri, Hafid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007501/
https://www.ncbi.nlm.nih.gov/pubmed/21588089
http://dx.doi.org/10.1107/S1600536810028515
_version_ 1782194372786257920
author Meskini, Ihssan
Daoudi, Maria
Daran, Jean-Claude
Ben Hadda, Taibi
Zouihri, Hafid
author_facet Meskini, Ihssan
Daoudi, Maria
Daran, Jean-Claude
Ben Hadda, Taibi
Zouihri, Hafid
author_sort Meskini, Ihssan
collection PubMed
description The asymmetric unit of the title polymer, {[Na(4)(C(15)H(14)N(2)O(4))(2)]·7.5H(2)O}(n), contains two 2-[(3,5-dimethyl-1H-pyrazol-1-yl)(phen­yl)meth­yl]propane­dioate (ppmp) anions, eight water mol­ecules (one located on a twofold rotation axis) and five sodium cations (one located on an inversion center and the other one located on a twofold rotation axis). The carboxyl­ate groups of the ppmp anions and the water mol­ecules bridge the Na cations, forming a two-dimensional polymeric structure. In the structure there are two types of coordination environment around the metal cations: one Na cation is coordinated by five O atoms in a distorted square-pyramidal geometry while the other four Na cations are coordinated by six O atoms in a distorted octa­hedral geometry. Extensive O—H⋯O and O—H⋯N hydrogen bonding is present in the crystal structure. The H atoms of one methyl group of the ppmp anion are disordered equally over two positions.
format Text
id pubmed-3007501
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30075012010-12-30 Poly[[bis­{μ(3)-2-[(3,5-dimethyl-1H-pyrazol-1-yl)(phen­yl)meth­yl]propane­dioato}tetra­sodium(I)] 7.5-hydrate] Meskini, Ihssan Daoudi, Maria Daran, Jean-Claude Ben Hadda, Taibi Zouihri, Hafid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title polymer, {[Na(4)(C(15)H(14)N(2)O(4))(2)]·7.5H(2)O}(n), contains two 2-[(3,5-dimethyl-1H-pyrazol-1-yl)(phen­yl)meth­yl]propane­dioate (ppmp) anions, eight water mol­ecules (one located on a twofold rotation axis) and five sodium cations (one located on an inversion center and the other one located on a twofold rotation axis). The carboxyl­ate groups of the ppmp anions and the water mol­ecules bridge the Na cations, forming a two-dimensional polymeric structure. In the structure there are two types of coordination environment around the metal cations: one Na cation is coordinated by five O atoms in a distorted square-pyramidal geometry while the other four Na cations are coordinated by six O atoms in a distorted octa­hedral geometry. Extensive O—H⋯O and O—H⋯N hydrogen bonding is present in the crystal structure. The H atoms of one methyl group of the ppmp anion are disordered equally over two positions. International Union of Crystallography 2010-07-24 /pmc/articles/PMC3007501/ /pubmed/21588089 http://dx.doi.org/10.1107/S1600536810028515 Text en © Meskini et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Meskini, Ihssan
Daoudi, Maria
Daran, Jean-Claude
Ben Hadda, Taibi
Zouihri, Hafid
Poly[[bis­{μ(3)-2-[(3,5-dimethyl-1H-pyrazol-1-yl)(phen­yl)meth­yl]propane­dioato}tetra­sodium(I)] 7.5-hydrate]
title Poly[[bis­{μ(3)-2-[(3,5-dimethyl-1H-pyrazol-1-yl)(phen­yl)meth­yl]propane­dioato}tetra­sodium(I)] 7.5-hydrate]
title_full Poly[[bis­{μ(3)-2-[(3,5-dimethyl-1H-pyrazol-1-yl)(phen­yl)meth­yl]propane­dioato}tetra­sodium(I)] 7.5-hydrate]
title_fullStr Poly[[bis­{μ(3)-2-[(3,5-dimethyl-1H-pyrazol-1-yl)(phen­yl)meth­yl]propane­dioato}tetra­sodium(I)] 7.5-hydrate]
title_full_unstemmed Poly[[bis­{μ(3)-2-[(3,5-dimethyl-1H-pyrazol-1-yl)(phen­yl)meth­yl]propane­dioato}tetra­sodium(I)] 7.5-hydrate]
title_short Poly[[bis­{μ(3)-2-[(3,5-dimethyl-1H-pyrazol-1-yl)(phen­yl)meth­yl]propane­dioato}tetra­sodium(I)] 7.5-hydrate]
title_sort poly[[bis­{μ(3)-2-[(3,5-dimethyl-1h-pyrazol-1-yl)(phen­yl)meth­yl]propane­dioato}tetra­sodium(i)] 7.5-hydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007501/
https://www.ncbi.nlm.nih.gov/pubmed/21588089
http://dx.doi.org/10.1107/S1600536810028515
work_keys_str_mv AT meskiniihssan polybism3235dimethyl1hpyrazol1ylphenylmethylpropanedioatotetrasodiumi75hydrate
AT daoudimaria polybism3235dimethyl1hpyrazol1ylphenylmethylpropanedioatotetrasodiumi75hydrate
AT daranjeanclaude polybism3235dimethyl1hpyrazol1ylphenylmethylpropanedioatotetrasodiumi75hydrate
AT benhaddataibi polybism3235dimethyl1hpyrazol1ylphenylmethylpropanedioatotetrasodiumi75hydrate
AT zouihrihafid polybism3235dimethyl1hpyrazol1ylphenylmethylpropanedioatotetrasodiumi75hydrate