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Poly[[bis{μ(3)-2-[(3,5-dimethyl-1H-pyrazol-1-yl)(phenyl)methyl]propanedioato}tetrasodium(I)] 7.5-hydrate]
The asymmetric unit of the title polymer, {[Na(4)(C(15)H(14)N(2)O(4))(2)]·7.5H(2)O}(n), contains two 2-[(3,5-dimethyl-1H-pyrazol-1-yl)(phenyl)methyl]propanedioate (ppmp) anions, eight water molecules (one located on a twofold rotation axis) and five sodium cations (one located on an inversion ce...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007501/ https://www.ncbi.nlm.nih.gov/pubmed/21588089 http://dx.doi.org/10.1107/S1600536810028515 |
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author | Meskini, Ihssan Daoudi, Maria Daran, Jean-Claude Ben Hadda, Taibi Zouihri, Hafid |
author_facet | Meskini, Ihssan Daoudi, Maria Daran, Jean-Claude Ben Hadda, Taibi Zouihri, Hafid |
author_sort | Meskini, Ihssan |
collection | PubMed |
description | The asymmetric unit of the title polymer, {[Na(4)(C(15)H(14)N(2)O(4))(2)]·7.5H(2)O}(n), contains two 2-[(3,5-dimethyl-1H-pyrazol-1-yl)(phenyl)methyl]propanedioate (ppmp) anions, eight water molecules (one located on a twofold rotation axis) and five sodium cations (one located on an inversion center and the other one located on a twofold rotation axis). The carboxylate groups of the ppmp anions and the water molecules bridge the Na cations, forming a two-dimensional polymeric structure. In the structure there are two types of coordination environment around the metal cations: one Na cation is coordinated by five O atoms in a distorted square-pyramidal geometry while the other four Na cations are coordinated by six O atoms in a distorted octahedral geometry. Extensive O—H⋯O and O—H⋯N hydrogen bonding is present in the crystal structure. The H atoms of one methyl group of the ppmp anion are disordered equally over two positions. |
format | Text |
id | pubmed-3007501 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30075012010-12-30 Poly[[bis{μ(3)-2-[(3,5-dimethyl-1H-pyrazol-1-yl)(phenyl)methyl]propanedioato}tetrasodium(I)] 7.5-hydrate] Meskini, Ihssan Daoudi, Maria Daran, Jean-Claude Ben Hadda, Taibi Zouihri, Hafid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title polymer, {[Na(4)(C(15)H(14)N(2)O(4))(2)]·7.5H(2)O}(n), contains two 2-[(3,5-dimethyl-1H-pyrazol-1-yl)(phenyl)methyl]propanedioate (ppmp) anions, eight water molecules (one located on a twofold rotation axis) and five sodium cations (one located on an inversion center and the other one located on a twofold rotation axis). The carboxylate groups of the ppmp anions and the water molecules bridge the Na cations, forming a two-dimensional polymeric structure. In the structure there are two types of coordination environment around the metal cations: one Na cation is coordinated by five O atoms in a distorted square-pyramidal geometry while the other four Na cations are coordinated by six O atoms in a distorted octahedral geometry. Extensive O—H⋯O and O—H⋯N hydrogen bonding is present in the crystal structure. The H atoms of one methyl group of the ppmp anion are disordered equally over two positions. International Union of Crystallography 2010-07-24 /pmc/articles/PMC3007501/ /pubmed/21588089 http://dx.doi.org/10.1107/S1600536810028515 Text en © Meskini et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Meskini, Ihssan Daoudi, Maria Daran, Jean-Claude Ben Hadda, Taibi Zouihri, Hafid Poly[[bis{μ(3)-2-[(3,5-dimethyl-1H-pyrazol-1-yl)(phenyl)methyl]propanedioato}tetrasodium(I)] 7.5-hydrate] |
title | Poly[[bis{μ(3)-2-[(3,5-dimethyl-1H-pyrazol-1-yl)(phenyl)methyl]propanedioato}tetrasodium(I)] 7.5-hydrate] |
title_full | Poly[[bis{μ(3)-2-[(3,5-dimethyl-1H-pyrazol-1-yl)(phenyl)methyl]propanedioato}tetrasodium(I)] 7.5-hydrate] |
title_fullStr | Poly[[bis{μ(3)-2-[(3,5-dimethyl-1H-pyrazol-1-yl)(phenyl)methyl]propanedioato}tetrasodium(I)] 7.5-hydrate] |
title_full_unstemmed | Poly[[bis{μ(3)-2-[(3,5-dimethyl-1H-pyrazol-1-yl)(phenyl)methyl]propanedioato}tetrasodium(I)] 7.5-hydrate] |
title_short | Poly[[bis{μ(3)-2-[(3,5-dimethyl-1H-pyrazol-1-yl)(phenyl)methyl]propanedioato}tetrasodium(I)] 7.5-hydrate] |
title_sort | poly[[bis{μ(3)-2-[(3,5-dimethyl-1h-pyrazol-1-yl)(phenyl)methyl]propanedioato}tetrasodium(i)] 7.5-hydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007501/ https://www.ncbi.nlm.nih.gov/pubmed/21588089 http://dx.doi.org/10.1107/S1600536810028515 |
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