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(N-Benzoyl-N′-phenylthiourea-κS)chlorido(η(4)-1,5-cyclooctadiene)rhodium(I)
The title compound, [RhCl(C(8)H(12))(C(14)H(12)N(2)OS)], is a rhodium(I) derivative with a functionalized thiourea ligand. Despite the presence of several heteroatoms, the thiourea ligand coordinates only in a monodentate fashion via the S atom. The geometry of the coordination sphere is approxima...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007502/ https://www.ncbi.nlm.nih.gov/pubmed/21588103 http://dx.doi.org/10.1107/S1600536810029740 |
| _version_ | 1782194373062033408 |
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| author | Kotze, P. D. Riekert Roodt, Andreas Venter, Johan A. Otto, Stefanus |
| author_facet | Kotze, P. D. Riekert Roodt, Andreas Venter, Johan A. Otto, Stefanus |
| author_sort | Kotze, P. D. Riekert |
| collection | PubMed |
| description | The title compound, [RhCl(C(8)H(12))(C(14)H(12)N(2)OS)], is a rhodium(I) derivative with a functionalized thiourea ligand. Despite the presence of several heteroatoms, the thiourea ligand coordinates only in a monodentate fashion via the S atom. The geometry of the coordination sphere is approximately square planar about the Rh(I) atom, with two bonds to the π-electrons of the 1,5-cyclooctadiene ligand, one bond to the Cl(−) ligand and one bond to the S atom of the thiourea ligand. The molecular structure is stabilized by intramolecular N—H⋯O and N—H⋯Cl hydrogen bonding. Intermolecular N—H⋯O hydrogen-bonding interactions lead to the formation of layers extending parallel to (011). |
| format | Text |
| id | pubmed-3007502 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30075022010-12-30 (N-Benzoyl-N′-phenylthiourea-κS)chlorido(η(4)-1,5-cyclooctadiene)rhodium(I) Kotze, P. D. Riekert Roodt, Andreas Venter, Johan A. Otto, Stefanus Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [RhCl(C(8)H(12))(C(14)H(12)N(2)OS)], is a rhodium(I) derivative with a functionalized thiourea ligand. Despite the presence of several heteroatoms, the thiourea ligand coordinates only in a monodentate fashion via the S atom. The geometry of the coordination sphere is approximately square planar about the Rh(I) atom, with two bonds to the π-electrons of the 1,5-cyclooctadiene ligand, one bond to the Cl(−) ligand and one bond to the S atom of the thiourea ligand. The molecular structure is stabilized by intramolecular N—H⋯O and N—H⋯Cl hydrogen bonding. Intermolecular N—H⋯O hydrogen-bonding interactions lead to the formation of layers extending parallel to (011). International Union of Crystallography 2010-07-31 /pmc/articles/PMC3007502/ /pubmed/21588103 http://dx.doi.org/10.1107/S1600536810029740 Text en © Kotze et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Kotze, P. D. Riekert Roodt, Andreas Venter, Johan A. Otto, Stefanus (N-Benzoyl-N′-phenylthiourea-κS)chlorido(η(4)-1,5-cyclooctadiene)rhodium(I) |
| title | (N-Benzoyl-N′-phenylthiourea-κS)chlorido(η(4)-1,5-cyclooctadiene)rhodium(I) |
| title_full | (N-Benzoyl-N′-phenylthiourea-κS)chlorido(η(4)-1,5-cyclooctadiene)rhodium(I) |
| title_fullStr | (N-Benzoyl-N′-phenylthiourea-κS)chlorido(η(4)-1,5-cyclooctadiene)rhodium(I) |
| title_full_unstemmed | (N-Benzoyl-N′-phenylthiourea-κS)chlorido(η(4)-1,5-cyclooctadiene)rhodium(I) |
| title_short | (N-Benzoyl-N′-phenylthiourea-κS)chlorido(η(4)-1,5-cyclooctadiene)rhodium(I) |
| title_sort | (n-benzoyl-n′-phenylthiourea-κs)chlorido(η(4)-1,5-cyclooctadiene)rhodium(i) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007502/ https://www.ncbi.nlm.nih.gov/pubmed/21588103 http://dx.doi.org/10.1107/S1600536810029740 |
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