cis-Bis(1,10-phenanthroline-κ(2) N,N′)bis­(thio­cyanato-κN)magnesium(II)

The title compound, [Mg(NCS)(2)(C(12)H(8)N(2))(2)], has been synthesized from the hydro­thermal reaction of MgCl(2), KSCN, 1,10-phenanthroline and H(2)O. Its structure is isotypic with the Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) analogues. The Mg(II) cation has a slightly distorted octa­he...

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Detalles Bibliográficos
Autores principales: Zhao, Dan, Li, Fei-Fei, Sha, Jiao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007504/
https://www.ncbi.nlm.nih.gov/pubmed/21588209
http://dx.doi.org/10.1107/S1600536810027054
Descripción
Sumario:The title compound, [Mg(NCS)(2)(C(12)H(8)N(2))(2)], has been synthesized from the hydro­thermal reaction of MgCl(2), KSCN, 1,10-phenanthroline and H(2)O. Its structure is isotypic with the Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) analogues. The Mg(II) cation has a slightly distorted octa­hedral geometry containing four N atoms from two 1,10-phenanthroline mol­ecules and two N atoms from two thio­cyanate anions. The asymmetric unit contains one-half mol­ecule, and the complete complex has 2 symmetry.

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