cis-Bis(1,10-phenanthroline-κ(2) N,N′)bis­(thio­cyanato-κN)magnesium(II)

The title compound, [Mg(NCS)(2)(C(12)H(8)N(2))(2)], has been synthesized from the hydro­thermal reaction of MgCl(2), KSCN, 1,10-phenanthroline and H(2)O. Its structure is isotypic with the Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) analogues. The Mg(II) cation has a slightly distorted octa­he...

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Detalles Bibliográficos
Autores principales: Zhao, Dan, Li, Fei-Fei, Sha, Jiao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007504/
https://www.ncbi.nlm.nih.gov/pubmed/21588209
http://dx.doi.org/10.1107/S1600536810027054
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author Zhao, Dan
Li, Fei-Fei
Sha, Jiao
author_facet Zhao, Dan
Li, Fei-Fei
Sha, Jiao
author_sort Zhao, Dan
collection PubMed
description The title compound, [Mg(NCS)(2)(C(12)H(8)N(2))(2)], has been synthesized from the hydro­thermal reaction of MgCl(2), KSCN, 1,10-phenanthroline and H(2)O. Its structure is isotypic with the Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) analogues. The Mg(II) cation has a slightly distorted octa­hedral geometry containing four N atoms from two 1,10-phenanthroline mol­ecules and two N atoms from two thio­cyanate anions. The asymmetric unit contains one-half mol­ecule, and the complete complex has 2 symmetry.
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spelling pubmed-30075042010-12-30 cis-Bis(1,10-phenanthroline-κ(2) N,N′)bis­(thio­cyanato-κN)magnesium(II) Zhao, Dan Li, Fei-Fei Sha, Jiao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mg(NCS)(2)(C(12)H(8)N(2))(2)], has been synthesized from the hydro­thermal reaction of MgCl(2), KSCN, 1,10-phenanthroline and H(2)O. Its structure is isotypic with the Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) analogues. The Mg(II) cation has a slightly distorted octa­hedral geometry containing four N atoms from two 1,10-phenanthroline mol­ecules and two N atoms from two thio­cyanate anions. The asymmetric unit contains one-half mol­ecule, and the complete complex has 2 symmetry. International Union of Crystallography 2010-07-21 /pmc/articles/PMC3007504/ /pubmed/21588209 http://dx.doi.org/10.1107/S1600536810027054 Text en © Zhao et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Dan
Li, Fei-Fei
Sha, Jiao
cis-Bis(1,10-phenanthroline-κ(2) N,N′)bis­(thio­cyanato-κN)magnesium(II)
title cis-Bis(1,10-phenanthroline-κ(2) N,N′)bis­(thio­cyanato-κN)magnesium(II)
title_full cis-Bis(1,10-phenanthroline-κ(2) N,N′)bis­(thio­cyanato-κN)magnesium(II)
title_fullStr cis-Bis(1,10-phenanthroline-κ(2) N,N′)bis­(thio­cyanato-κN)magnesium(II)
title_full_unstemmed cis-Bis(1,10-phenanthroline-κ(2) N,N′)bis­(thio­cyanato-κN)magnesium(II)
title_short cis-Bis(1,10-phenanthroline-κ(2) N,N′)bis­(thio­cyanato-κN)magnesium(II)
title_sort cis-bis(1,10-phenanthroline-κ(2) n,n′)bis­(thio­cyanato-κn)magnesium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007504/
https://www.ncbi.nlm.nih.gov/pubmed/21588209
http://dx.doi.org/10.1107/S1600536810027054
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AT shajiao cisbis110phenanthrolinek2nnbisthiocyanatoknmagnesiumii

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