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Bis(acetylacetonato-κ(2) O,O′)[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex
The title complex, [Cu(0.31)Ni(0.69)(C(5)H(7)O(2))(2)], was isolated from the reaction of bis(N,N-dimethyaminoethanol)copper(II) with bis(acetylacetonato)nickel(II), which yielded crystals with mixed sites at the central metal position; the refined copper–nickel occupancy ratio is 0.31 (4):0.69 ...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007506/ https://www.ncbi.nlm.nih.gov/pubmed/21588179 http://dx.doi.org/10.1107/S160053681002756X |
| _version_ | 1782194373982683136 |
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| author | Shahid, Muhammad Hamid, Mazhar Mazhar, Muhammad Azad Malik, Mohammad Raftery, James |
| author_facet | Shahid, Muhammad Hamid, Mazhar Mazhar, Muhammad Azad Malik, Mohammad Raftery, James |
| author_sort | Shahid, Muhammad |
| collection | PubMed |
| description | The title complex, [Cu(0.31)Ni(0.69)(C(5)H(7)O(2))(2)], was isolated from the reaction of bis(N,N-dimethyaminoethanol)copper(II) with bis(acetylacetonato)nickel(II), which yielded crystals with mixed sites at the central metal position; the refined copper–nickel occupancy ratio is 0.31 (4):0.69 (4). Two acetylacetonate ligands, related by a centre of symmetry, are coordinated to the central metal atom in a square-planar configuration while the methyne C atoms of the acetylacetonate ligands, ca 3.02 Å away, are orthogonal to this plane at the metal site. |
| format | Text |
| id | pubmed-3007506 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30075062010-12-30 Bis(acetylacetonato-κ(2) O,O′)[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex Shahid, Muhammad Hamid, Mazhar Mazhar, Muhammad Azad Malik, Mohammad Raftery, James Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(0.31)Ni(0.69)(C(5)H(7)O(2))(2)], was isolated from the reaction of bis(N,N-dimethyaminoethanol)copper(II) with bis(acetylacetonato)nickel(II), which yielded crystals with mixed sites at the central metal position; the refined copper–nickel occupancy ratio is 0.31 (4):0.69 (4). Two acetylacetonate ligands, related by a centre of symmetry, are coordinated to the central metal atom in a square-planar configuration while the methyne C atoms of the acetylacetonate ligands, ca 3.02 Å away, are orthogonal to this plane at the metal site. International Union of Crystallography 2010-07-17 /pmc/articles/PMC3007506/ /pubmed/21588179 http://dx.doi.org/10.1107/S160053681002756X Text en © Shahid et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Shahid, Muhammad Hamid, Mazhar Mazhar, Muhammad Azad Malik, Mohammad Raftery, James Bis(acetylacetonato-κ(2) O,O′)[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex |
| title | Bis(acetylacetonato-κ(2)
O,O′)[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex |
| title_full | Bis(acetylacetonato-κ(2)
O,O′)[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex |
| title_fullStr | Bis(acetylacetonato-κ(2)
O,O′)[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex |
| title_full_unstemmed | Bis(acetylacetonato-κ(2)
O,O′)[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex |
| title_short | Bis(acetylacetonato-κ(2)
O,O′)[copper(II)nickel(II)(0.31/0.69)]: a mixed-metal complex |
| title_sort | bis(acetylacetonato-κ(2)
o,o′)[copper(ii)nickel(ii)(0.31/0.69)]: a mixed-metal complex |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007506/ https://www.ncbi.nlm.nih.gov/pubmed/21588179 http://dx.doi.org/10.1107/S160053681002756X |
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