Chloridometh­yl(2-methyl­quinolin-8-olato-κ(2) N,O)phenyl­tin(IV)

The asymmetric unit of the title complex, [Sn(CH(3))(C(6)H(5))(C(10)H(8)NO)Cl], consists of two independent mol­ecules, both of which have the N,O-chelated Sn(IV) atom in a cis-C(2)SnNOCl trigonal-bipyramidal geometry [C—Sn—C = 124.82 (8) and 137.69 (8)°]. The Cl atom of the mol­ecule with the small...

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Detalles Bibliográficos
Autores principales: Vafaee, Maryam, Amini, Mostafa M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007514/
https://www.ncbi.nlm.nih.gov/pubmed/21588190
http://dx.doi.org/10.1107/S1600536810027790
Descripción
Sumario:The asymmetric unit of the title complex, [Sn(CH(3))(C(6)H(5))(C(10)H(8)NO)Cl], consists of two independent mol­ecules, both of which have the N,O-chelated Sn(IV) atom in a cis-C(2)SnNOCl trigonal-bipyramidal geometry [C—Sn—C = 124.82 (8) and 137.69 (8)°]. The Cl atom of the mol­ecule with the smaller C—Sn—C angle inter­acts weakly with the Sn(IV) atom of the mol­ecule with the wider C—Sn—C angle at an Sn⋯Cl distance of 3.595 (1) Å. Weak inter­molecular C—H⋯O and C—H⋯Cl hydrogen bonding is present in the crystal structure.

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